Establishment of heterolytic and homolytic Y-NO2 bond dissociation energy scales of nitro-containing compounds in acetonitrile: Chemical origin of NO2 release and capture
(Chemical Equation Presented) The first heterolytic and homolytic N(O)-NO2 bond dissociation energy scales of three types Y-nitro (Y = N, O) compounds and corresponding radical anions in acetonitrile were established by using titration calorimetry combined with relevant electrochemical data through proper thermodynamic cycles.
The alkylation of the N-nitrobenzenesulfonamide potassium salt by alkyl halides in DMFA leads predominantly to N-alkyl-N-nitrobenzenesulfonamides.It was discovered that the alkylation reaction is reversible.Increase in the volume of the cation in the sulf
Ivshin, V. P.,Ivshina, T. N.,Bakhtin, K. I.,Tsaregorodtsev, S. V.
p. 1316 - 1318
(2007/10/02)
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