cas 59854-11-4, TERT-BUTYL 3-HYDROXYPROPIONATE | Articles data ｜lookchem

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59854-11-4

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Stable free radical polymerization - Acrylate alkoxyamine synthesis
An efficient synthesis of the alkoxyamine containing a benzoyl peroxide fragment, one tert-butyl acrylate monomer unit and TEMPO via an oxymercuration reaction followed by an oxidative demercuration reaction is reported. The formation of significant amounts of an undesired reduced product with the latter reaction was overcome by using a milder reducing agent (NaBH3CN) than those (NaBH4, LiBH4) reported to work well in other systems.
Lukkarila, Julie L.,Hamer, Gordon K.,Georges, Michael K.
p. 5317 - 5319
(2004)
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Chemical Properties

Boiling Point: 215.7°C at 760 mmHg
Flash Point:83.8°C
Density: 0.990 g/mL at 20 °C(lit.)
Vapor Pressure: 0.0316mmHg at 25°C
Refractive Index: n20/D 1.424
PKA: 14.33±0.10(Predicted)
BRN: 1854888
PSA: 46.53000
LogP: 0.71050

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