Thermal Oxidative Deamination of Aliphatic Amines to Aldehydes with Bis(diphenylphosphinyl) Peroxide
Reaction of N-substituted alkylamines having pseudoacidic hydrogen at the 1-methylene group with bis(diphenylphosphinyl) peroxide yields the deaminated products by thermal elimination of diphenylphosphinic acid from the intermediate O-diphenylphosphinylhydroxylamines.
Masse, Guy,Sturtz, Georges
p. 907 - 910
(2007/10/02)
Aminomethylation of N-propargylphosphoramides. Synthesis of unsymmetrical acetylenic diamines
The preparation of N-alkyl-N-(4-dialkylamino-2-butylnyl)phosphoramides 3 using the Mannich reaction is described.The acidic hydrolysis of those phosphoramides leads to unsymmetrical acetylenic diamines 4.
Corbel, Bernard,Paugam, Jean-Paul,Sturtz, Georges
p. 2183 - 2188
(2007/10/02)
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