Thermal C-H Activation Catalyzed by RhCl(CH2=CH2)(PMe3)2. Hydrogen Transfer from Cycloalkanes to Ethylene and Ethylene Insertion into Cycloalkanes
Dehydrogenation of cycloalkanes to cycloalkenes is catalyzed by RhCl(CH2=CH2)(PMe3)2 under ethylene pressure at a high temperature over 170 deg C.Ethylene insertion into sp3 C-H bond of cycloalkanes occurs at 230 deg C to afford ethylcycloalkanes.
Sakakura, Toshiyasu,Tanaka, Masato
p. 359 - 362
(2007/10/02)
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