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6164-86-9

The 1,3,5-trinitrobenzene-pyrene charge transfer complex is a chemical compound formed through the interaction between 1,3,5-trinitrobenzene (TNB) and pyrene. TNB is an organic compound with three nitro groups attached to a benzene ring, while pyrene is a polycyclic aromatic hydrocarbon consisting of four fused benzene rings. In this complex, electrons are transferred from the pyrene molecule to the TNB molecule, creating a charge transfer interaction. This results in a new compound with unique properties, such as altered electronic structure and spectroscopic characteristics. The formation of this complex is of interest in various fields, including materials science, organic chemistry, and supramolecular chemistry, as it can provide insights into the behavior of charge transfer complexes and their potential applications in areas like sensors, solar cells, and organic electronics.

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  • 6164-86-9 Structure

  • Basic information

    1. Product Name: 1,3,5-trinitrobenzene - pyrene charge transfer complex
    2. Synonyms: 1,3,5-trinitrobenzene - pyrene charge transfer complex
    3. CAS NO:6164-86-9
    4. Molecular Formula:
    5. Molecular Weight: 415.362
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 6164-86-9.mol
    9. Article Data: 2

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: 1,3,5-trinitrobenzene - pyrene charge transfer complex(CAS DataBase Reference)
    10. NIST Chemistry Reference: 1,3,5-trinitrobenzene - pyrene charge transfer complex(6164-86-9)
    11. EPA Substance Registry System: 1,3,5-trinitrobenzene - pyrene charge transfer complex(6164-86-9)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 6164-86-9(Hazardous Substances Data)

6164-86-9 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 6164-86-9 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 6,1,6 and 4 respectively; the second part has 2 digits, 8 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 6164-86:
(6*6)+(5*1)+(4*6)+(3*4)+(2*8)+(1*6)=99
99 % 10 = 9
So 6164-86-9 is a valid CAS Registry Number.

6164-86-9Relevant articles and documents

Charge Transfer Complexes of Pyrene with Dinitro- and Trinitrobenzene Acceptors

Ayad, Mohamad M.

, p. 123 - 134 (2007/10/02)

The charge transfer (CT) compexes formed between pyrene with some Dinitrobenzenes (DNB) and 1,3,5-Trinitrobenzene (TNB) acceptors are studied in solution and solid state using UV-visible, infrared and fluorescence spectroscopies.The equilibrium constants (Kc) for these complexes in solution have been calculated.The values of Kc follow the order o-DNB > m-DNB p-DNB TNB.This order is explained by considering the role that steric effects may play in the CT complex formation.In addition, the fluorescence quenching of pyrene with different acceptors is investigated.The effect of medium viscosity and temperature on the efficiency of quenching is also studied.Finally, the electrical properties for the solid CT complexes are measured. - Keywords: Pyrene CT complexes / Equilibrium constants / Fluorescence quenching / Electrical conductivity

ELECTRON-ATTRACTING PROPERTIES OF FUNCTIONALIZED TRINITROBENZENES: SPECTROSCOPIC AND CALORIMETRIC STUDY OF CRYSTALLINE COMPLEXES WITH POLYNUCLEAR AROMATIC HYDROCARBONS

Casellato, Fulvia,Mascherpa, Achille,Turrio, Luigi,Girelli, Alberto

, p. 587 - 592 (2007/10/02)

The variation of the electron-accepting capability of functionalized trinitrobenzenes with changing functional group has been studied.The formation of charge-transfer complexes with polynuclear aromatic hydrocarbons appears to be affected more by steric hindrance of the functional groups than by their electron-withdrawing properties.The CT values of substituted trinitrobenzene-polynuclear aromatic hydrocarbon complexes is neither correlable with the electronic properties of functional groups nor with the Hammett ?p parameter.

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