A Facile Synthesis of 2- and 3-Hydroxyalkylseleno Compounds
2-Hydroxyethylseleno and 3-hydroxypropylseleno compounds (selenides 6-9) have been prepared in good yields employing 2-hydroxyethyl and 3-hydroxypropyl selenocyanates (4 and 5).Several types of electrophilic substrates that reacted with the selenolate anions generated from 4 and 5 in situ in the presence of sodium borohydride included alkyl, benzylic, activated aromatic, benzoyl, and picolinyl halides.
Kang, Sang-Ihn,Spears, Colin Paul
p. 133 - 135
(2007/10/02)
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