Synthesis of α-Functionalized Trichloromethylcarbinols
A new series of α-functionalized trichloromethylcarbinols have been synthesized from corresponding α-halomethyl ketones, esters, and amides in 48-78% overall yields. Reactivity of nitrates obtained in the first step was dependent on the electron-withdrawi
Ram, Ram N.,Soni, Vineet Kumar
p. 8922 - 8928
(2015/09/15)
THE USE OF NITRATE ESTERS IN THE SYNTHESIS OF DI- AND TRI-CARBONYL COMPOUNDS
Vicinal di- and tri-carbonyl compounds are prepared by reacting some electrophiles, bearing a C=O vicinal to the leaving group, with an anion exchanger, in the nitrate form, or with the ammonium salt n-Bu4N(+)NO3(-).
Cainelli, Gianfranco,Manescalchi, Francesco,Plessi, Laura
p. 163 - 164
(2007/10/02)
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