A biomimetic electrocatalytic system for the atom-economical chemoselective synthesis of secondary amines
A facile one-pot oxidation-imine formation-reduction route to secondary amines can be achieved electrolytically from primary amines. This atom-economical 1ox-mediated sequence, leaving ammonia as the sole byproduct, allows the rapid chemoselect
Largeron, Martine,Fleury
supporting information; experimental part
p. 883 - 886
(2009/07/25)
Rapid reduction of nitriles to primary amines with nickel boride at ambient temperature
Reduction of a variety of nitriles to their corresponding primary amines can be achieved with nickel boride generated in situ in dry ethanol at ambient temperature. The reductions are very rapid and chemoselective.
Khurana, Jitender M.,Kukreja, Gagan
p. 1265 - 1269
(2007/10/03)
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