cas 67613-13-2, p-Pentyl-p'-carboxamide | Articles data

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LOW TRANSITION TEMPERTURE LIQUID CRYSTALLINE AMINES INCORPORATING THE BIPHENYL RING SYSTEM.
N-(n-butyl)-4-n-pentyl-4 prime -biphenylamine has an enantiotropic smectic A phase between 45 and 78 degree . 4-n-pentyl-4 prime -biphenylmethanamine has a monotropic smectic phase from 63-56 degree . These compounds, together with the previously reported phenylcyclohexane analogs, are the first examples of liquid crystalline amines not involving intramolecular hydrogen bonding or extensive conjugative interactions.
MacMillan,Labes
p. 51 - 56
(1979)
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Efficient nitrile hydration mediated by RuII catalysts in micellar media
Efficient nitrile hydration to the corresponding amide derivatives is observed in water using poorly soluble [RuCl2(η6- arene)(PR3)] catalysts 1 with the aid of surfactants to ensure substrate and catalyst solubilization, and enabling ligand effect study on catalytic activity. Amide yields of 40 to 95% can be observed with a variety of aromatic and aliphatic nitriles using the optimized catalyst system, [RuCl 2(p-cymene)(PPh2OEt)]/Triton X-114. Catalyst separation and recycling is possible.
Cavarzan, Alessandra,Scarso, Alessandro,Strukul, Giorgio
experimental part
p. 790 - 794
(2010/09/05)

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