A boron-based synthesis of the natural product (+)-trans- dihydrolycoricidine
Diastereoselective diboration results in the highly selective 1,4-dihydroxylation of chiral cyclohexadienes (see scheme). Together with the catalytic enantioselective conjugate allylboration, the diene diboration facilitates the asymmetric synthesis of the cytotoxic agent (+)-trans- dihydrolycoricidine (1). pin=pinacol. Copyright
Poe, Sarah L.,Morken, James P.
supporting information; experimental part
p. 4189 - 4192
(2011/06/20)
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