Reprint of: Nitrile functionalized organogermane chalcogenide clusters with hetero-(nor-)adamantane cores
By the synthesis of Cl3Ge(CH2)2CN (1) and subsequent reaction with sodium monochalcogenides, adamantane-type [(NC(CH2)2Ge)4Ch6] (Ch = S (2), Se) and noradamantane-type [(NC(CHsu
Nitrile functionalized organogermane chalcogenide clusters with hetero-(nor-)adamantane cores Dedicated to Professor Heinrich Lang on the occasion of his 60th birthday.
By the synthesis of Cl3Ge(CH2)2CN (1) and subsequent reaction with sodium monochalcogenides, adamantane-type [(NC(CH2)2Ge)4Ch6] (Ch = S (2), Se) and noradamantane-type [(NC(CH2)2Ge)4Te5] (3) were obtained. The compounds represent the first nitrile-functionalized tetrel chalcogenide clusters and the first nitrile-functionalized clusters of the named architectures, and are thus potential precursor for novel reaction pathways to multifunctional core-shell compounds.
Heimann, Samuel,Thiele, Günther,Dehnen, Stefanie
p. 36 - 40
(2016/04/26)
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