- Reactions of dichlorocarbene and arenesulfenyl chlorides with 3,4-epoxy-1-butene and vinylethylene carbonate
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Reaction of 3,4-epoxy-1-butene with dichlorocarbene is accompanied by deoxygenation and yields a mixture of 1,1-dichloro-2-vinylcyclopropane, 2,2,2',2'-tetrachlorobicyclopropyl, and 2,2-dichlorocyclopropyloxirane. Arenesulfenyl chlorides react with 3,4-epoxy-1-butene to afford both Markownikoff and anti-Markownikoff addition products, whereas vinylethylene carbonate gives rise exclusively to the anti-Markownikoff adducts.
- Mannafov,Berdnikov,Samuilov
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p. 339 - 344
(2007/10/03)
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