- On the planarity of styrene and its derivatives: The molecular structures of styrene and (Z)-β-bromostyrene as determined by ab initio calculations and gas-phase electron diffraction
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The molecular structures of styrene and (Z)-β-bromostyrene have been studied in the gas phase at nozzle temperatures of 303 and 338 K respectively. For both molecules the electron diffraction data were consistent with the results from ab initio calculatio
- Cochran, John C.,Hagen, Kolbjorn,Paulen, Gunnar,Shen, Quang,Tom, Samson,Traetteberg, Marit,Wells, Christopher
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p. 313 - 326
(2007/10/03)
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- Bromation stereoselective d'alcynes par le tribromure de tetrabutylammonium
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The reaction of tetrabutylammonium tribromide (TBABr3) with alkynes (R-CC-R', with R and (or) R'=H, alkyl, phenyl, carboxyl, carbonyl) in chloroform at 20 deg C gives only the corresponding E 1,2-dibromo alkene in high yields.A mechanism involving a cy
- Berthelot, Jacques,Fournier, Michel
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p. 603 - 607
(2007/10/02)
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