Novel Conversion of Epoxides to One Carbon Homologated Allylic Alcohols by Dimethylsulfonium Methylide
The reaction of excess of dimethylsulfonium methylide with terminal, allylic, or benzylic epoxides affords good to excellent yields of one carbon homologated allylic alcohols.
Alcaraz, L.,Harnett, J. J.,Mioskowski, C.,Martel, J. P.,Gall, T. Le,et al.
p. 5449 - 5452
(2007/10/02)
STEREOCHEMICAL OUTCOME OF THE REACTION OF SOME α-SELENOALKYLLITHIUMS WITH 4-t-BUTYL CYCLOHEXANONE
α-selenoalkyllithiums were found to have a high propensity to add to 4-t-butyl cyclohexanone in an equatorial mode.Stereochemical assignments are discussed.
Labar, D.,Krief, A.,Norberg, B.,Evrard, G.,Durant, F.
p. 1083 - 1100
(2007/10/02)
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