1,1′-Diborylferrocenes from [2]Boraferrocenophanes by boron-boron exchange
The reactivity of [2]boraferrocenophane [(η5-C 5H4)-BNMe2-BNMe2-(η5- C5H4)Fe] (3) with borane and diborane compounds was examined, resulting in the complete loss of th
Ir-catalyzed C-H activation in the synthesis of borylated ferrocenes and half sandwich compounds
The complex generated from 1/2 [Ir(OMe)(cod)]2 and 4,4′-di-tert-butyl-2,2′-bipyridine catalyzes the regioselective borylation of ferrocenes, CpMn(CO)3 and CpMo(CO)3CH 3 with a stoichiometric amount of B2pin2.
Datta, Anupama,Koellhofer, Axel,Plenio, Herbert
p. 1508 - 1509
(2007/10/03)
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