Indenylnickel imidato complexes: Synthesis, characterization, and reactivities
The complex (1-Me-indenyl)Ni(PPh3)(phthalimidate) has been prepared and fully characterized by IR and 1H, 13C{1H}, and 31P{1H} NMR spectroscopy and single-crystal X-ray diffraction. The ana
Structural and NMR studies of indenyl hapticity and rotational barriers in the complexes (η-1-R-indenyl)Ni(PPh3)(X) (R = H, Me; X = Cl, Me)
The relative trans influences of Cl and Me in the complexes (1-Me-indenyl)Ni(PPh3)Cl and (1-Me-indenyl)Ni(PPh3)Me lead to different solid state hapticities for the 1-Me-indenyl ligands. Comparing the solution NMR data for these compl