STEREOSPECIFIC FORMATION OF AMIDINES BY 1,1-ADDITION OF AMINES TO ISOCYANIDES
Addition of secondary amines to isonitriles in the presence of AgCl at low temperature gives isolable but thermodynamically unstable Z-amidines; only the more stable 6E undergoes ring expansion to the imidazoline 7.
Hegarty, Anthony F.,Chandler, Anne
p. 885 - 888
(2007/10/02)
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