cas 748777-12-0, (2S,3R)-Methyl 2-(4-methoxyphenyl)pyrrolidine-3-carboxylate | Articles data ｜lookchem

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748777-12-0

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The Cyano Group as a Traceless Activation Group for the Intermolecular [3+2] Cycloaddition of Azomethine Ylides: A Five-Step Synthesis of (±)-Isoretronecanol
The cyano group was used as a traceless activation group for the [3+2] cycloaddition of azomethine ylides in a two-step process, thereby providing a highly effective approach to 5-unsubstituted pyrrolidines. The transformation includes the silver acetate
Li, Jundong,Zhao, Huaibo,Jiang, Xunjin,Wang, Xiance,Hu, Haiming,Yu, Lei,Zhang, Yandong
p. 6306 - 6310
(2015/05/20)

Synthesis of cis-2-aryl-3-pyrrolidine carboxylic esters via diastereoselective cyclization of γ-imino esters using a TiCl 4/Et3N reagent system
Facile synthesis of cis-2-aryl-3-pyrrolidine carboxylates from readily accessible γ-imino esters by intramolecular cyclization mediated by a TiCl4/Et3N reagent system is described.
Suresh, Surisetti,Periasamy, Mariappan
p. 6291 - 6293
(2007/10/03)

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Chemical Properties

Boiling Point: 342.8°C at 760 mmHg
Flash Point:161.1°C
Density: 1.117g/cm³
Storage Temp.:2-8°C
Vapor Pressure: 7.36E-05mmHg at 25°C
Refractive Index: 1.518
PKA: 9.11±0.10(Predicted)
PSA: 47.56000
LogP: 1.84760

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