- Visible light-induced co- or cu-catalyzed selenosulfonylation of alkynes: Synthesis of β-(seleno)vinyl sulfones
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A visible light-induced Co- or Cu-catalyzed selenosulfonylation of alkynes for the synthesis of β-(seleno)vinyl sulfones is demonstrated. This method utilizes a low-cost cobalt salt or metal copper as the catalysts. The reaction goes through a photoinduced free radical addition of selenosulfonates to alkynes for the 1,2-selenosulfonylation of alkynes under mild conditions.
- Ji, Shun-Jun,Wang, Shun-Yi,Xu, Pei,Zhang, Rong
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- REACTIONS OF SULFOHYDRAZIDES WITH BENZENESELENIC ACID, SELENIUM HALIDES, AND SULFUR HALIDES. A CONVENIENT PREPARATION OF SELENOSULFONATES AND THIOSULFONATES
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The oxidation of sulfohydrazides with benzeneselenic acid provides an efficient and convenient preparation of selenosulfonates.Se-Phenyl p-tolueneselenosulfonates was also produced in good to excellent yield from the reaction of p-toluenesulfohydrazide with PhSeCl, PhSeBr, or PhSeCl3.Sulfohydrazide react with sulfenyl halides or with PhSBr3 to produce thiosulfonates generally high yield.The treatment of p-toluenesulfohydrazide with benzenetellurinic acid, PhTeCl3, or PhTeBr3, afforded only diphenyl ditelluride and not the corresponding tellerosulfonate.
- Back, Thomas G.,Collins, Scott,Krishna, M. Vijaya
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- Removal of Thioacetal Protecting Groups by Benzeneseleninic Anhydride
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A number of thioacetals were deprotected with benzeneseleninic anhydride in good yield.The reaction worked particularly well for hindered spiro-1,3-dithiolans of 2,2,6-trimethylcyclohexanone and fenchone, and in examples where other literature methods had failed.
- Cussans, Nigel J.,Ley, Steven V.,Barton, Derek H. R.
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p. 1654 - 1657
(2007/10/02)
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- A convenient synthesis of selenolsulfonates from the oxidation of sulfonhydrazides with benzeneseleninic acid
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The reaction of sulfonhydrazides with benzeneseleninic acid furnishes selenolsulfonates in high yield.
- Back, Thomas G.,Collins, Scott
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p. 2213 - 2214
(2007/10/02)
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