cas 782-27-4, 4-(5,6,7,8-tetrahydronaphthalen-2-yl)butanoic acid | Articles data ｜lookchem

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782-27-4

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The thermodynamic properties of 4-methylphenanthrene
Measurements leading to the calculation of the ideal-gas thermodynamic properties for 4-methylphenanthrene are reported.Thermochemical and thermophysical properties were determined by adiabatic heat-capacity calorimetry, combustion calorimetry, comparative ebulliometry, and inclined-piston manometry.Results were used to calculate entropies, enthalpies, and Gibbs energies of formation for the ideal-gas state at selected temperatures to 500 K.Group-contribution methods involving comparisons for a series of methyl-substituted aromatic molecules were used to demonstrate the consistency of ideal-gas entropies and the enthalpy of formation determined for 4-methylphenanthrene with literature values for related compounds.The results are shown to be in accord with a barrier to methyl rotation from the literature determined using n.m.r. spectroscopy.
Chirico, R. D.,Hossenlopp, I. A.,Nguyen, A.,Steele, W. V.,Gammon, B. E.
p. 179 - 202
(1989)
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The design, synthesis, and evaluation of novel conformationally rigid analogues of sialyl Lewis(x)
The design and synthesis of a series of analogues of sialyl Lewis(x) (1) which incorporate conformationally rigid tetralin and naphthalene ring systems (2-4) has led to novel compounds which have similar potency to 1 as inhibitors of cell adhesion. Copyright (C) 1998 Elsevier Science Ltd.
Murphy, Paul V.,Hubbard, Rod E.,Manallack, David T.,Wills, Ruth E.,Montana, John G.,Taylor, Richard J. K.
p. 2421 - 2439
(2007/10/03)

Tricyclic aromatic ketones by cycliacylation of carboxylic acid derivatives of indan, tetralin, and benzosuberane
The synthesis of a homologous series of new carboxylic acids substituted in the α-position of indan, tetralin, and benzosuberane is accomplished using an efficient general procedure.Cycliacylation of these acids and their corresponding β-isomers produces a complete series of tricyclic aromatic ketones.
Isabelle, M. Elaine,Wightman, Robert H.,Avdovich, Hajro W.,Laycock, David E.
p. 1344 - 1349
(2007/10/02)

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Chemical Properties

Melting Point: 47-49 °C
Boiling Point: 378.7°C at 760 mmHg
Flash Point:275.6°C
Density: 1.109g/cm³
Vapor Pressure: 2.07E-06mmHg at 25°C
PKA: 4.77±0.10(Predicted)
PSA: 37.30000
LogP: 2.97270

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