- Cobalt-Catalyzed Diastereoselective Cross-Couplings between Alkynylzinc Pivalates and Functionalized Cyclic Iodides or Bromides
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Various 1,2-, 1,3-, and 1,4-substituted cyclic iodides or bromides undergo highly diastereoselective cross-couplings (diastereoselectivity (dr) up to 99:1) with a range of alkynylzinc pivalates, using CoCl2 (20 mol%) and trans-N,N,N′,N′-tetrame
- Thomas, Lucie,Lutter, Ferdinand H.,Hofmayer, Maximilian S.,Karaghiosoff, Konstantin,Knochel, Paul
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- A FACILE PROCEDURE FOR THE DIRECT CONVERSION OF ETHERS TO ALKYL IODIDES
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Treatment of ethers with phenyl dichlorophosphate and sodium iodide in refluxing xylenes or acetonitrile resulted in the cleavage of the ether linkage leading to the formation of alkyl iodides.
- Liu, Hsing-Jang,Wiszniewski, Virginia
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p. 119 - 124
(2007/10/02)
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