One-pot synthesis of hybrid macrocyclic pentamers with variable functionalizations around the periphery
Chemical equations presented. Rather than four- or six-residue macrocylces, one-pot macrocyclization allows for the highly selective formation of five-residue macrocycles rigidified by intramolecular hydrogen bonds. Variable functionalizations around the
Highly selective one-pot synthesis of H-bonded pentagon-shaped circular aromatic pentamers
One-pot, multi-molecular macrocyclization allows the highly selective preparation of pentagon-shaped circular aromatic pentamers mediated by an inward-pointing continuous hydrogen-bonding network.