- DISPROPORTIONATION OF HYDROGEN IN 3-CARENE
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The disproportionation of hydrogen in 3-carene takes place with the formation of compounds of the 1,1,4-trimethylcycloheptane series.The proposed reaction mechanism involves dehydration of the 2-carene to 2,4-caradiene, which exists in a rapid tautomeric equilibrium with 3,7,7-trimethyl-1,3,5-cycloheptatriene.This gives rise to the appearance of compounds with a seven-membered ring in the reaction product.
- Manukov, E. N.,Chuiko, V. A.,Vyglazov, O. G.
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p. 257 - 262
(2007/10/02)
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