Stereoselective Synthesis of the 6-Phosphono Analogue of Fructose-6-phosphate
The non-isosteric phosphono analogue 2 of D-fructose-6-phosphate has been synthesized exploiting the reactivity of the fructose derivative 7 which is easily available on a large scale from saccharose; introduction ofthe phosphonic group by Arbuzov reactio
Sucrose Chemistry. A Synthetically Useful Monoarenesulfonation
The reaction of sucrose with 2,4,6-triisopropylbenzenesulfonyl chloride (tripsyl chloride) occured preferentially at the 6'-OH group yielding crystalline 6'-O-tripsylsucrose (2a) in 39percent yield without chromatography.The structure of 2a was proven by
Singh, Sujan,Maynard, Christopher M.,Doyle, Ronald J.,Taylor, K. Grant
p. 976 - 981
(2007/10/02)
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