FUNCTIONALIZATION OF SATURATED HYDROCARBONS IN THE PRESENCE OF APROTIC ORGANIC SUPERACIDS. 2. SINGLE-STAGE SYNTHESIS OF THIOESTERS R1CO-SR FROM n-ALKANES OR CYCLOALKANES (RH), ELEMENTAL SULFUR, AND COMPLEXES R1COBr*2AlBr3
It has been found for the first time that n-alkanes and cycloalkanes (RH) can interact with elemental sulfur at ca. 20 deg C.These reactions go forward in the presence of aprotic organic superacids with the composition R1CO-SR in satisfactory yields.
Orlinkov, A. V.,Akhrem, I. S.,Afanas'eva, L. V.,Vitt, S. V.,Vol'pin, M. E.
p. 90 - 92
(2007/10/02)
More Articles about upstream products of 89896-84-4