CaII, YbII and SmII Bis(Amido) Complexes Coordinated by NHC Ligands: Efficient Catalysts for Highly Regio- and Chemoselective Consecutive Hydrophosphinations with PH3
The first example of intermolecular hydrophosphination of styrene, 2-vinylpyridine and phenylacetylene with PH3 catalyzed by bis-(amido) complexes [(Me3Si)2N]2M(NHC)2 (M=Ca, Yb, Sm) coordinated by NHC
Lapshin, Ivan V.,Basalov, Ivan V.,Lyssenko, Konstantin A.,Cherkasov, Anton V.,Trifonov, Alexander A.
p. 459 - 463
(2019/01/04)
Radical addition of secondary phosphine chalcogenides to allylamine: Atom-economic synthesis of aminopropylphosphine chalcogenides
Secondary phosphine sulfides and phosphine selenides react with allylamine under the conditions of radical initiation (UV or AIBN) to form the anti-Markovnikov adducts in up to 93 % yield.