Palladium-catalyzed nucleophilic substitution of diarylmethyl carbonates with malonate carbanions
The nucleophilic substitution of diarylmethyl carbonates with malonate carbanions proceeded in the presence of [Pd(π-C3H 5)(cod)]BF4-Cy-Xantphos, giving the desired (diarylmethyl)malonates in up to 90% yield. The yield was extremely affected by choice of the phosphine ligand. Copyright
Kuwano, Ryoichi,Kusano, Hiroki
p. 528 - 529
(2008/02/10)
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