Total synthesis of 2-arachidonylglycerol (2-Ara-Gl)
Total synthesis of 2-Arachidonylglycerol (2-Ara-Gl) was accomplished starting from arachidonic acid and glycerol. The sequence involves selective protection of the primary alcohols of glycerol, esterification, and mild hydrolysis of the protecting groups. A unique hydrolysis condition was developed to prevent isomerization of the 2-Ara-Gl to the more stable 1- monoglyceride.
Han, Luning,Razdan, Raj K.
p. 1631 - 1634
(2007/10/03)
CHEMOSELEKTIVE MONO- UND DISILYLETHERBILDUNG AUS TERTIAEREN UND SEKUNDAEREN SILANEN
Tertiary and secondary silanes are O-selective.With alcohols the corresponding silyl ethers are formed.Cesium fluoride/imidazole)CsF/Im) is a better activating system than CsF alone.Primary OH groups are silylated remarkably faster under CsF/Im activation
Horner, Leopold,Mathias, Johann
p. 155 - 174
(2007/10/02)
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