27012-22-2

Basic information

• Product Name: 5-METHYL-2-PHENYL-PYRIDINE
• Synonyms: 5-METHYL-2-PHENYL-PYRIDINE;2-PHENYL-5-METHYLPYRIDINE;Einecs 248-163-9
• CAS NO: 27012-22-2
• Molecular Formula: C₁₂H₁₁N
• Molecular Weight: 169.22
• EINECS: 248-163-9
• Mol File: 27012-22-2.mol
• Article Data: 76

Chemical Properties

• Melting Point: 53.0 to 57.0 °C
• Boiling Point: 166°C/16mmHg(lit.)
• Flash Point: 121.1°C
• Appearance: /
• Density: 1.03g/cm³
• Vapor Pressure: 0.00422mmHg at 25°C
• Refractive Index: 1.568
• Storage Temp.: Sealed in dry,Room Temperature
• PKA: 4.73±0.10(Predicted)
• CAS DataBase Reference: 5-METHYL-2-PHENYL-PYRIDINE(CAS DataBase Reference)
• NIST Chemistry Reference: 5-METHYL-2-PHENYL-PYRIDINE(27012-22-2)
• EPA Substance Registry System: 5-METHYL-2-PHENYL-PYRIDINE(27012-22-2)

Safety Data

• Hazardous Substances Data: 27012-22-2(Hazardous Substances Data)

Usage

Synthesis Reference(s)

Tetrahedron Letters, 17, p. 383, 1976 DOI: 10.1016/S0040-4039(00)93738-9

InChI:InChI=1/C12H11N/c1-10-7-8-12(13-9-10)11-5-3-2-4-6-11/h2-9H,1H3

Upstream product

• 3510-66-5 2-Bromo-5-methylpyridine 
• 98-80-6 phenylboronic acid 
• 108-99-6 3-Methylpyridine 
• 591-50-4 iodobenzene 
• 109-72-8 n-butyllithium 
• 66562-51-4 5-Methyl-2-phenyl-2,5-dihydropyridin 
• 591-51-5 phenyllithium 
• 108-88-3 toluene 
• 98-88-4 benzoyl chloride 
• 18368-64-4 2-chloro-5-methylpyridine 
• 100-58-3 phenylmagnesium bromide 
• 50488-42-1 2-bromo-5-(trifluoromethyl)pyridine 
• 884494-43-3 2-(2-methoxyphenyl)-5-methyl-pyridine 
• 18368-65-5 4-methylpyridine-2-thiol 

Downstream Products

• 945267-56-1 C₄₂H₃₉N₃O₃ 
• 1421006-66-7 (E)-5-methyl-2-(2-(2-methylstyryl)phenyl)pyridine 
• 1498234-69-7 methyl 4-(hydroxy(2-(5-methylpyridin-2-yl)phenyl)amino)benzoate 
• 1613027-81-8 tert-butyl [2-(5-methylpyridin-2-yl)phenyl]carbamate 
• 155617-73-5 2-(5-methylpyridin-2-yl)benzonitrile 
• 1574299-42-5 C₁₉H₁₇NO 
• 1584673-24-4 5-methyl-2-(2-(phenylthio)phenyl)pyridine 
• 1379667-31-8 4-methyl-N-[2-(5-methylpyridin-2-yl)phenyl]benzenesulfonamide 
• 145218-22-0 ethyl 2-(5-methylpyridin-2-yl)benzoate 

Relevant articles and documents

A mechanistic investigation of an Iridium-catalyzed asymmetric hydrogenation of pyridinium salts

NMR studies of the catalyst, deuteration experiments, mass spectrometry, and isolation and characterization of intermediates, allow us to propose an outer-sphere mechanism for the Iridium-catalyzed asymmetric hydrogenation of N-alkyl-2-arylpyridinium salts.

A facile and versatile electro-reductive system for hydrodefunctionalization under ambient conditions

A general electrochemical system for reductive hydrodefunctionalization is described, employing the inexpensive and easily available triethylamine (Et3N) as a sacrificial reductant. This protocol is characterized by facile operation, sustainable conditions, and exceptionally wide substrate scope covering the cleavage of C-halogen, N-S, N-C, O-S, O-C, C-C and C-N bonds. Notably, the selectivity and capability of reduction can be conveniently switched by simple incorporation or removal of an alcohol as a co-solvent.

Compound, luminescent layer guest material, organic electroluminescent device and display device

The invention provides a compound as shown in a general formula (I). The compoundcan be used for an organic electroluminescent device as a guest material of a luminescent layer. The compound comprises a natural heterocyclic ring and iridium (Ir) coordinated structure, and the light emitting wavelength of the compound can be effectively regulated and controlled. When the compound is used as a guest material of a light-emitting layer, the light-emitting efficiency and the light stability of the organic electroluminescent device can be improved. In addition, the compound provided by the invention is small in molecular weight, is applied to a light-emitting layer, is relatively low in evaporation temperature, and is beneficial to processing. The invention also provides a luminescent layer guest material containing the compound shown in the general formula (I), an organic electroluminescent device and a display device.