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Home > Hot Product_List > CYCLOPENTADIENYLMANGANESE TRICARBONYL

Basic information

  • Name:
  • Manganese, tricarbonyl(h5-2,4-cyclopentadien-1-yl)-

  • Superlist Name:
  • Cyclopentadienylmanganese tricarbonyl
  • CAS No.:
  • 12079-65-1

  • Molecular Structure:
  • Formula:
  • C8H5MnO3
  • Molecular Weight:
  • 204.07
  • Synonyms:
  • Cyclopentadienylmanganesetricarbonyl (6CI);Manganese, tricarbonyl-p-cyclopentadienyl- (8CI);Cyclopentadienyl-p-tricarbonylmanganese;Cyclopentadienyltricarbonylmanganese;Cymantrene;Manganesecyclopentadienyltricarbonyl;Tricarbonyl(h5-cyclopentadienyl)manganese;Tricarbonyl-p-cyclopentadienylmanganese;Tricarbonylcyclopentadienylmanganese;h5-Cyclopentadienylmanganese tricarbonyl;p-Cyclopentadienylmanganesetricarbonyl;
  • EINECS:
  • 235-142-4
  • Melting Point:
  • 72-76 °C(lit.)
  • Appearance:
  • yellow crystals or crystalline chunks
  • Hazard Symbols:
  • VeryT+
  • Risk Codes:
  • 28
  • Safety Description:
  • 28-36/37-45 Details
  • Transport Information:
  • UN 2811 6.1/PG 2

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Chemistry

Product Name: Cyclopentadienylmanganese tricarbonyl (CAS NO.12079-65-1)


Molecular Formula: C8H5MnO3
Molecular Weight: 204.06g/mol
Mol File: 12079-65-1.mol
Einecs: 235-142-4
Appearance: Yellow crystals or crystalline chunks
Melting Point: 72-76 °C(lit.)
Boiling point: 41.5 °C at 760 mmHg
Sensitive: Air Sensitive
Enthalpy of Vaporization: 27.4 kJ/mol
Vapour Pressure: 418 mmHg at 25°C
H-Bond Donor: 0
H-Bond Acceptor: 4
Product Categories: ManganeseVapor Deposition Precursors; Catalysis and Inorganic Chemistry; Chemical Synthesis; Manganese; Precursors by Metal

Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LD50 intravenous 710ug/kg (0.71mg/kg)   U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. Vol. NX#11285,
mouse LD50 oral 150mg/kg (150mg/kg) BRAIN AND COVERINGS: "CHANGES IN CIRCULATION (HEMORRHAGE, THROMBOSIS, ETC.)"

AUTONOMIC NERVOUS SYSTEM: OTHER (DIRECT) PARASYMPATHOMIMETIC

BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD
Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 28(4), Pg. 29, 1963.
rat LCLo inhalation 120mg/m3/2H (120mg/m3) VASCULAR: BP LOWERING NOT CHARACTERIZED IN AUTONOMIC SECTION

BLOOD: HEMORRHAGE

LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES
Hygiene and Sanitation Vol. 30(4-6), Pg. 40, 1965.
rat LD50 intraperitoneal 14mg/kg (14mg/kg) BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD

LUNGS, THORAX, OR RESPIRATION: DYSPNEA

LUNGS, THORAX, OR RESPIRATION: CHRONIC PULMONARY EDEMA
Toxicology. Vol. 34, Pg. 341, 1985.
rat LD50 oral 22mg/kg (22mg/kg)   Toxicology. Vol. 34, Pg. 341, 1985.

Consensus Reports

Reported in EPA TSCA Inventory. Manganese and its compounds are on the Community Right-To-Know List.

Safety Profile

A poison by ingestion, inhalation, intraperitoneal, and intravenous routes. A mild narcotic which can damage kidneys. When heated to decomposition it emits acrid smoke and irritating fumes. See also MANGANESE COMPOUNDS and CARBON MONOXIDE.
Safety Information of Cyclopentadienylmanganese tricarbonyl (CAS NO.12079-65-1):
Hazard Codes: T+
Risk Statements: 28 
28:  Very Toxic if swallowed
Safety Statements: 28-36/37-45
28:  After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer)
36:  Wear suitable protective clothing  
37:  Wear suitable gloves 
45:  In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)

Standards and Recommendations

OSHA PEL: TWA 0.1 mg(Mn)/m3 (skin)
ACGIH TLV: TWA 0.1 mg(Mn)/m3

Specification

 Cyclopentadienylmanganese tricarbonyl ,its CAS NO. is 12079-65-1,the synonyms is (Eta5-Cyclopentadienyl) manganese tricarbonyl ; Cyclopentadienyl-p-tricarbonylmanganese ; Cyklopentadientrikarbonylmanganium ; Cymantrene ; Manganese, cyclopentadienyltricarbonyl- ; Manganese, tricarbonyl-pi-cyclopentadienyl- ; manganese,cyclopentadienyltricarbonyl ; Manganese,tricarbonyl(η5-2,4-cyclopentadien-1-yl)- .

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