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Cadmium sulfate

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Name

Cadmium sulfate

EINECS 233-331-6
CAS No. 10124-36-4 Density 3.09
PSA 88.64000 LogP -0.25970
Solubility 1130 g/L (20 °C) in water Melting Point 41 °C
Formula CdSO4 Boiling Point 330 °C at 760 mmHg
Molecular Weight 208.46 Flash Point N/A
Transport Information UN 2570 6.1/PG 3 Appearance White crystalline powder
Safety 53-45-60-61 Risk Codes 45-46-60-61-25-26-48/23/25-50/53
Molecular Structure Molecular Structure of 10124-36-4 (Cadmium sulfate) Hazard Symbols VeryT+; DangerousN
Synonyms

Cadmiummonosulfate;Cadmium sulfate (Cd(SO4));Cadmium sulforicum;

 

Cadmium sulfate Consensus Reports

NTP 10th Report on Carcinogens. IARC Cancer Review: Group 1 IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 58 , 1993,p. 119.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; Animal Sufficient Evidence IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 2 , 1973,p. 74.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; Animal Sufficient Evidence IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 11 , 1976,p. 39.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; Animal Sufficient Evidence IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 58 , 1993,p. 119.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; Human Sufficient Evidence IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 58 , 1993,p. 119.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) . Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program. Cadmium and its compounds are on the Community Right-To-Know List.

Cadmium sulfate Standards and Recommendations

OSHA PEL: TWA 5 μg(Cd)/m3
ACGIH TLV: TWA 0.002 mg(Cd)/m3 (respirable dust), Suspected Human Carcinogen); BEI: 5 μg/g creatinine in urine; 5 μg/L in blood
DFG MAK: Animal Carcinogen, Suspected Human Carcinogen
NIOSH REL: (Cadmium) Reduce to lowest feasible level

Cadmium sulfate Specification

The Cadmium sulfate (1:1), with the CAS registry number 10124-36-4 and EINECS registry number 233-331-6, has the IUPAC name of cadmium(2+) sulfate. It is a kind of white crystalline powder which is highly soluble in water. It is also hygroscopic, and belongs to the follwing product categories: Inorganics; Cadmium Salts; CadmiumMetal and Ceramic Science; Chemical Synthesis; Salts; ACS GradeChemical Synthesis; Cadmium; Catalysis and Inorganic Chemistry; Essential Chemicals; Routine Reagents. And the molecular formula of this chemical is CdSO4.

The physical properties of Cadmium sulfate (1:1) are as followings: (1)ACD/LogP: -1.03; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): -5.53; (4)ACD/LogD (pH 7.4): -5.53; (5)ACD/BCF (pH 5.5): 1; (6)ACD/BCF (pH 7.4): 1; (7)#H bond acceptors: 4; (8)#H bond donors: 2; (9)#Freely Rotating Bonds: 0; (10)Polar Surface Area: 82.98 Å2; (11)Enthalpy of Vaporization: 62.94 kJ/mol; (12)Boiling Point: 330 °C at 760 mmHg; (13)Vapour Pressure: 3.35E-05 mmHg at 25°C.

Preparation of Cadmium sulfate (1:1): This anhydrous material can be prepared using sulphuric acid and 30% H2O2, And after a series of filtration, crystallization and dehydration, the product is obtained:
Cd + H2SO4 + H2O2 → CdSO4 + 2 H2O

Uses of Cadmium sulfate (1:1): It is used widely for the electroplating of cadmium in electronic circuits. It is also used for electrolyte in a Weston standard cell. And it is also a precursor to cadmium-based pigment such as cadmium sulfide.

You should be cautious while dealing with this chemical. It is toxic by inhalation and if swallowed, and may impair fertility and cause cancer and heritable genetic damage. It is also harm to the unborn child. What's more, it is very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Therefore, you had better take the following instructions: Avoid exposure - obtain special instruction before use; In case of accident or if you feel unwell, seek medical advice immediately (show label where possible); This material and/or its container must be disposed of as hazardous waste; Avoid release to the environment. Refer to special instructions safety data sheet.

You can still convert the following datas into molecular structure:
(1)SMILES: [Cd+2].[O-]S([O-])(=O)=O
(2)InChI: InChI=1/Cd.H2O4S/c;1-5(2,3)4/h;(H2,1,2,3,4)/q+2;/p-2
(3)InChIKey: QCUOBSQYDGUHHT-NUQVWONBAG

The toxicity data is as follows:

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
dog LDLo oral 105mg/kg (105mg/kg)   Environmental Quality and Safety, Supplement. Vol. 1, Pg. 1, 1975.
dog LDLo subcutaneous 27mg/kg (27mg/kg)   Environmental Quality and Safety, Supplement. Vol. 1, Pg. 1, 1975.
frog LDLo subcutaneous 105mg/kg (105mg/kg)   "Abdernalden's Handbuch der Biologischen Arbeitsmethoden." Vol. 4, Pg. 1317, 1935.
mouse LD50 intraperitoneal 6879ug/kg (6.879mg/kg)   Comptes Rendus Hebdomadaires des Seances, Academie des Sciences. Vol. 256, Pg. 1043, 1963.
mouse LD50 oral 88mg/kg (88mg/kg)   "Aktual'nye Problemy Gigieny Truda. Current Problems of Labor Hygiene," Tarasenko, N.Y., ed. Moscow, Pervyi Moskovskii Meditsinskii Inst., 1978Vol. -, Pg. 14, 1978.
rat LD50 oral 280mg/kg (280mg/kg)   "Aktual'nye Problemy Gigieny Truda. Current Problems of Labor Hygiene," Tarasenko, N.Y., ed. Moscow, Pervyi Moskovskii Meditsinskii Inst., 1978Vol. -, Pg. 14, 1978.

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