- Henry Reaction
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Henry Reaction (Nitroaldol Reaction)
L. Henry, Compt. Rend. 120, 1265 (1895); J. Kamlet, US 2151517 (1939).
Base-catalyzed aldol-type condensation, q.v., of nitroalkanes with aldehydes or ketones:
Application to sugars: R. Fernández et al., Carbohyd. Res. 247, 239 (1993). Reagent controlled asymmetric induction: H. Sasai et al., Tetrahedron Letters 34, 855 (1993); R. Chinchilla et al., Tetrahedron Asymmetry 5, 1393 (1994); R. S. Varma et al., Tetrahedron Letters 38, 5131 (1997); R. Ballini, G. Bosica, J. Org. Chem. 62, 425 (1997); V. J. Bulbule et al., Tetrahedron 55, 9325 (1999). Catalyst effects: I. Morao, F. P. Cossio, Tetrahedron Letters 38, 6461 (1997); P. B. Kisanga, J. G. Verkade, J. Org. Chem. 64, 4298 (1999); D. Simoni et al., Tetrahedron Letters 41, 1607 (2000). Review: G. i, Comp. Org. Syn. 2, 321-340 (1991). Cf. Knoevenagel Condensation.
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