- Sakurai Reaction
-
Sakurai Reaction (Hosomi-Sakurai Reaction)
A. Hosomi, H. Sakurai, Tetrahedron Letters 1976, 1295; A. Hosomi et al., Chem. Letters 1976, 941.
Lewis acid-promoted nucleophilic addition of allylic silanes to carbon electrophiles accompanied by regiospecific transposition of the allylic moiety:
Synthetic applications: I. E. Markó, D. J. Bayston, Tetrahedron Letters 34, 6595 (1993); H. Hioki et al., ibid. 6131. [TiCp2(OSO2CF3)2] as catalyst: T. K. Hollis et al., ibid. 4309. Reviews: I. Fleming et al., Org. React. 37, 57-575 (1989); Y. Yamamoto, N. Sasaki, “The Stereochemistry of the Sakurai Reaction” in Stereochemistry of Organometallic and Inorganic Compounds vol. 3, I. Bernal, Ed. (Elsevier, New York, 1989) pp 363-437; I. Fleming, Comp. Org. Syn. 2, 563-593 (1991).
Prev: Houdry Cracking Process
Next: Hooker Reaction - 【Back】【Close 】【Print】【Add to favorite 】
- Related information
- Reaction routes of Metronidazole
- Reaction Kettle_008
- Production of 4-(2-Bromo-2-propenyl)-4-methyl-γ-butyrolactone by the Reaction of Ethyl levulinate with (2-bromoallyl)diisopropoxyborane
- Double Hydroxylation Reaction: 16α-Methylcortexolone
- Diels-Alder reaction: (1S-endo)-3-(Bicyclo[2.2.1]hept-5-en-2-ylcarbonyl)-2-oxazolidinone
- 4-(2-Bromo-2-propenyl)-4-methyl-gamma-butyrolactone: from the reaction of Ethyl levulinate and (2-Bromoallyl)diisopropoxyborane
- Synthesis of trans-4,4'-Dibromostilbene by a Double Heck Reaction of (Arylazo)amines with Vinyltriethoxysilane
- Single Displacement Reactions
- Reaction Design
- Chemical Reaction Stoichiometry (CRS, Tutorial, Java Applet, and Resources)
-
Health and Chemical more >
-
Hot Products
- 110-65-6 2-Butyne-1,4-diol
- 178446-02-1 2-Piperidinecarboxylic acid, 1-(3,3-dimethyl-1,2-dioxopentyl)-, (1R)-1-[3-(carboxymethoxy)phenyl]-3-(3,4-dimethoxyphenyl)propyl ester, (2S)-
- 573-97-7 1-Bromo-2-naphthol
- 90387-75-0 Glycine, N-(2-aminoethyl)-N-(2-hydroxyethyl)-, N-C12-20 acyl derivs., monosodium salts
- 6728-26-3 TRANS-2-HEXENAL
- 68606-06-4 Fatty acids, vegetable-oil, potassium sodium salts
- 199111-50-7 AEM 5772
- 329736-05-2 DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL][(1S,2S)-(-)-1,2-DIPHENYLETHYLENEDIAMINE]RUTHENIUM (II)
- 594-70-7 2-Methyl-2-nitropropane
- 56683-54-6 11-Hexadecen-1-ol,(11Z)-
- 1210344-83-4 Ertugliflozin
- 31643-49-9 4-Nitrophthalonitrile