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Cas Database |
| Name |
Cyclopropylamine |
EINECS | 212-142-2 |
| CAS No. | 765-30-0 | Density | 0.938 g/cm3 |
| PSA | 26.02000 | LogP | 0.80780 |
| Solubility | Miscible with water, ethanol,ether and chloroform. | Melting Point |
-50 °C |
| Formula | C3H7N | Boiling Point | 49.3 °C at 760 mmHg |
| Molecular Weight | 57.0953 | Flash Point | -14 °F |
| Transport Information | UN 2733 3/PG 2 | Appearance | Clear and colourless, volatile liquid |
| Safety | 16-26-36/37/39-45-33-7/9 | Risk Codes | 11-22-34-36/37 |
| Molecular Structure |
|
Hazard Symbols |
 F,  C,  Xi
|
| Synonyms |
Cyclopropanamine;Aminocyclopropane; |
Article Data | 40 |
Cyclopropylamine Synthetic route
- 13021-02-8
nitrocyclopropane
- 765-30-0
Cyclopropylamine
| Conditions | Yield |
|---|---|
| With triethylamine In water at 80℃; for 6h; Inert atmosphere; Green chemistry; chemoselective reaction; | 91% |
| With hydrogenchloride; iron | |
| With methanol; nickel Hydrogenation; |
| Conditions | Yield |
|---|---|
| With sodium hydroxide; sodium hypochlorite; water at 31 - 103℃; Conversion of starting material; Hofmann Rearrangement; Heating / reflux; | 62% |
| With bromine dann man behandelt mit Kalilauge und destilliert mit Wasserdampf; | |
| zur Bildung; |
- 73330-91-3
Methyl N-cyclopropylcarbamate
- 765-30-0
Cyclopropylamine
| Conditions | Yield |
|---|---|
| With potassium hydroxide |
- 765-30-0
Cyclopropylamine
| Conditions | Yield |
|---|---|
| With 1,2-dimethoxyethane; trifluoroacetic anhydride und anschliessend mit KOH in wss. Aethylenglykol; |
| Conditions | Yield |
|---|---|
| With hydrogen azide; chloroform; sulfuric acid |
- 765-30-0
Cyclopropylamine
| Conditions | Yield |
|---|---|
| With sodium bis(2-methoxyethoxy)aluminium dihydride In toluene at 140℃; for 4h; |
- 27374-25-0
[(1-Ethoxycyclopropyl)oxy]trimethylsilane
- 765-30-0
Cyclopropylamine
| Conditions | Yield |
|---|---|
| With formic acid; C24H22N4*BF4(1-)*Ru(2+)*Cl(1-)*C10H14; ammonium formate In neat (no solvent) at 40℃; for 12h; Green chemistry; chemoselective reaction; |
- 765-30-0
Cyclopropylamine
| Conditions | Yield |
|---|---|
| Stage #1: diphenyl cyclopropylphosphoramidate With water; monoammonium para-toluenesulfonate; o-phthalic dicarboxaldehyde In acetonitrile at 90℃; for 24h; Sealed tube; Stage #2: With sodium hydroxide In water pH=8 - 9; chemoselective reaction; |
- 765-30-0
Cyclopropylamine
| Conditions | Yield |
|---|---|
| Stage #1: N-cyclopropyl-P,P-diphenylphosphinic amide With water; monoammonium para-toluenesulfonate; o-phthalic dicarboxaldehyde In acetonitrile at 90℃; for 24h; Sealed tube; Stage #2: With sodium hydroxide In water pH=8 - 9; chemoselective reaction; |
| Conditions | Yield |
|---|---|
| With 20 μM Tris pH 9.0 buffer at 25℃; Rate constant; |
Cyclopropylamine Chemical Properties
Cyclopropylamine is the chemical compound with the formula C3H7N.Its molar weight is 57.09.
Cyclopropylamine chemical structural formula is 
.
Synonyms Aminocyclopropane
CAS Registry Number 765-30-0
EINECS 212-142-2
Density 0.824
Melting point -50 oC
Boiling point 49-50 oC
Refractive index 1.419-1.422
Flash point 1 oC
Refractive index : n20/D 1.420(lit.)
Storage temp : Flammables area
Cyclopropylamine Safety Profile
A very dangerous fire hazard when exposed to heat or flame. When heated to decomposition it emits toxic fumes of NOx. Hazard Symbols : F 
C 
The Risk Statements information of Cyclopropylamine R11:Highly flammable;R22:Harmful if swallowed.;R34:Causes burns;
The Safety Statements information of Cyclopropylamine S16:Keep away from sources of ignition - No smoking.
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice;
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection;
S45:In case of accident of if you feel unwell, seek medical advice immediately (show the label where possible).
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