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Basic information

  • Name:
  • D(-)Prolinol

  • CAS No.:
  • 68832-13-3

  • Molecular Structure:
  • Formula:
  • C5H11NO
  • Molecular Weight:
  • 101.15
  • Synonyms:
  • D-prolinol;[(2R)-2,3,4,5-tetrahydropyrrol-2-yl]methanol;D-(-)-Prolinol;(R)-(-)-2-(Hydroxymethyl)pyrrolidine;(R)-(-)-2-Pyrrolidinemethanol;D-Pro-ol(oil);D-Prolinol(oil);
  • Density:
  • 0.978 g/cm3
  • Boiling Point:
  • 211 °C at 760 mmHg
  • Flash Point:
  • 86.1 °C
  • Appearance:
  • Colorless to light yellow liquid
  • Hazard Symbols:
  • IrritantXi
  • Risk Codes:
  • 36/37/38
  • Safety Description:
  • 26-36-24/25 Details

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Chemistry

Molecular Structure:

Molecular Formula: C5H11NO
Molecular Weight: 101.1469
IUPAC Name: [(2R)-Pyrrolidin-1-ium-2-yl]methanol
Synonyms of D(-)Prolinol (CAS NO.68832-13-3): (R)-(-)-2-(Hydroxymethyl)pyrrolidine ; R-2-Hydroxymethyl-pyrrolidine ; (R)-1-Pyrrolidin-2-yl-methanoL ; (R)-(-)-2-Pyrrolidinemethanol ; R-2-Pyrrolidinemethanol ; (R)-Pyrrolidine-2-methanol ; (R)-(-)-Prolinol ; (R)-Prolinol
CAS NO: 68832-13-3
Product Categories: Pharmaceutical Intermediates ; Proline [Pro, P] ; Amino Alcohols ; Chiral Building Blocks ; Glycidyl Compounds, etc. (Chiral) ; Synthetic Organic Chemistry ; Amino alcohols
Index of Refraction: 1.454
Molar Refractivity: 28.02 cm3
Molar Volume: 103.3 cm3
Surface Tension: 36.5 dyne/cm
Density: 0.978 g/cm3
Flash Point: 86.1 °C
Enthalpy of Vaporization: 52.03 kJ/mol
Boiling Point: 211 °C at 760 mmHg
Vapour Pressure: 0.0423 mmHg at 25°C

Uses

People always use D(-)Prolinol (CAS NO.68832-13-3) in broad variety of chemical reactions as chiral ligand, chiral catalyst or chiral auxiliary reagent in the Hajos-Parrish-Eder-Sauer-Wiechert reaction, the Baylis-Hillman reaction, Noyori type reaction and the Michael reaction.

Safety Profile

Hazard Codes of D(-)Prolinol (CAS NO.68832-13-3): IrritantXi
Risk Statements: 36/37/38
R36/37/38: Irritating to eyes, respiratory system and skin.
Safety Statements: 26-36-24/25
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S36: Wear suitable protective clothing. 
S24/25: Avoid contact with skin and eyes.
WGK Germany: 3
Hazard Note: Irritant/Air Sensitive

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