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Cas Database

Name	D-2-Phenylglycine	EINECS	212-876-3
CAS No.	875-74-1	Density	1.246 g/cm³
PSA	63.32000	LogP	1.47130
Solubility	0.3 g/100mL in water	Melting Point	302 °C (dec.)(lit.)
Formula	C₈H₉NO₂	Boiling Point	288.7 °C at 760 mmHg
Molecular Weight	151.165	Flash Point	128.4 °C
Transport Information	N/A	Appearance	white crystalline powder
Safety	22-24/25-45-36/37/39-26	Risk Codes	23/24/25-36/37/38
Molecular Structure		Hazard Symbols	T
Synonyms	Benzeneaceticacid, a-amino-, (R)-;(R)-a-Phenylglycine;D-(-)-2-Phenylglycine;D-(-)-Aminophenylacetic acid;D-(-)-Phenylglycine;D-(-)-a-Aminophenylacetic acid;D-(-)-a-Phenylglycine;D-2-Phenylglycine;D-C-Phenylglycine;D-Phenylglycine;D-a-Aminophenylacetic acid;Glycine,2-phenyl-, D- (8CI);(-)-(R)-Phenylglycine;(-)-Phenylglycine;(2R)-Amino-2-phenylethanoic acid;(R)-(-)-2-Phenylglycine;(R)-2-Amino-2-(phenyl)ethanoic acid;(R)-2-Amino-2-phenylacetic acid;(R)-2-Phenylglycine;(R)-Phenylglycine;	Article Data	90

D-2-Phenylglycine Synthetic route

: 29125-25-5
(R)-2-azido-2-phenylacetic acid

: 875-74-1
(R)-phenylglycine

Conditions

Conditions	Yield
With hydrogen; palladium on activated charcoal In water; acetic acid under 760 Torr; for 3h;	97%

: potassium cyanide

: 100-52-7
benzaldehyde

: 875-74-1
(R)-phenylglycine

Conditions

Conditions	Yield
With nitrilase AY487533 In aq. acetate buffer at 20℃; for 1h; pH=8; Enzymatic reaction; enantioselective reaction;	96.5%

: (R)-2-benzyloxycarbonylamino-2-phenylacetonitrile

: 875-74-1
(R)-phenylglycine

Conditions

Conditions	Yield
With hydrogenchloride; water In water at 110℃; for 3h; optical yield given as %ee;	94%

: 33125-05-2
Boc-D-Phg-OH

: 875-74-1
(R)-phenylglycine

Conditions

Conditions	Yield
With trifluoroacetic acid for 0.333333h;	89%
With hydrogenchloride; Dowex 50*8 1.) THF, room temperature, 2 h.; Yield given. Multistep reaction;

: 551-16-6
6-Aminopenicillanic Acid

: 700-63-0, 6485-52-5, 6485-67-2, 58429-87-1
(R)-phenylglycine amide

A: 875-74-1
(R)-phenylglycine

B: 69-53-4
ampicillin

Conditions

Conditions	Yield
With A. faecalis; immobilised penicillin acylase (EC 3.5.1.11) In water; acetonitrile at 0℃; Product distribution; Kinetics; Further Variations:; Solvents; reusing run; Enzymatic reaction;	A n/a B 86%

: 186801-10-5
N-(2,4,6-trimethyl-benzenesulfonyl)-D-phenylglycine

: 875-74-1
(R)-phenylglycine

Conditions

Conditions	Yield
With sodium naphthalenide In 1,2-dimethoxyethane at -40℃; for 0.5h;	78%

: 188772-75-0
(R)-(furan-2-yl)(phenyl)methanamine

: 875-74-1
(R)-phenylglycine

Conditions

Conditions	Yield
With ozone In methanol at -78℃; for 0.25h;	78%

: 14257-84-2, 15962-46-6, 29633-99-6, 42429-20-9
N-acetyl-α-phenylglycine

: 875-74-1
(R)-phenylglycine

Conditions

Conditions	Yield
With water at 30℃; for 26h; D-aminoacylase from Streptomyces tuirus IFO 13418;	74%

: 611-71-2, 611-72-3, 17199-29-0, 90-64-2
MANDELIC ACID

: 875-74-1
(R)-phenylglycine

Conditions

Conditions	Yield
With D-glucose; ammonia; ammonium chloride In aq. phosphate buffer at 30℃; for 24h; pH=8; Catalytic behavior; Reagent/catalyst; Microbiological reaction; Green chemistry; Enzymatic reaction; enantioselective reaction;	71%

: 133545-89-8
[(1R)-2-(benzyloxy)-2-oxo-1-phenylethyl]ammonium 4-methyl-1-benzensulfonate

: 875-74-1
(R)-phenylglycine

Conditions

Conditions	Yield
With hydrogenchloride Heating;	69%

D-2-Phenylglycine Chemical Properties

IUPAC Name: (2R)-2-azaniumyl-2-phenylacetate
Empirical Formula: C₈H₉NO₂
Molecular Weight: 151.1626g/mol
EINECS: 212-876-3
Structure of D-2-Phenylglycine (CAS NO.875-74-1):

Index of Refraction: 1.589
Molar Refractivity: 40.9 cm³
Molar Volume: 121.3 cm³
Polarizability: 16.21×10^-24cm³
Surface Tension: 57 dyne/cm
Density: 1.246 g/cm³
Flash Point: 128.4 °C
Enthalpy of Vaporization: 55.75 kJ/mol
Melting Point: 302 °C (dec.)(lit.)
Boiling Point: 288.7 °C at 760 mmHg
Vapour Pressure: 0.00107 mmHg at 25°C
Water Solubility: 0.3g/100mL
Product Categories: GLYCINESCAFFOLD;Pharmaceutical Intermediates;Amino ACIDS SERIES;Phenylglycine [Phg];Unusual Amino Acids;Amino Acids
Canonical SMILES: C1=CC=C(C=C1)C(C(=O)[O-])[NH3+]
Isomeric SMILES: C1=CC=C(C=C1)[C@H](C(=O)[O-])[NH3+]
InChI: InChI=1S/C8H9NO2/c9-7(8(10)11)6-4-2-1-3-5-6/h1-5,7H,9H2,(H,10,11)/t7-/m1/s1
InChIKey: ZGUNAGUHMKGQNY-SSDOTTSWSA-N

D-2-Phenylglycine Safety Profile

Hazard Codes: Toxic T
Risk Statements: 23/24/25-36/37/38
R23/24/25:Toxic by inhalation, in contact with skin and if swallowed.
R36/37/38:Irritating to eyes, respiratory system and skin.
Safety Statements: 22-24/25-45-36/37/39-26
S22:Do not breathe dust.
S24/25:Avoid contact with skin and eyes.
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection.
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
WGK Germany: 3
HS Code: 29224995

D-2-Phenylglycine Specification

D-2-Phenylglycine , its cas register number is 875-74-1. It also can be called Benzeneacetic acid, alpha-amino-, (alphaR)- ;
D-(-)-alpha-Phenylglycine . D-2-Phenylglycine (CAS NO.875-74-1) is a white crystalline powder.

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