DIMETHYL MALONATE (108-59-8),DIMETHYL MALONATE (108-59-8) Manufacturers & Suppliers,Synthesis,MSDS

Basic information

Name:
Propanedioicacid, 1,3-dimethyl ester
Superlist Name:
Dimethyl malonate
CAS No.:
108-59-8
Molecular Structure:
Formula:
C₅H₈O₄
Molecular Weight:
132.13
Synonyms:
Malonicacid, dimethyl ester (6CI,8CI);Propanedioic acid, dimethyl ester (9CI);Dimethyl 1,3-propanedioate;Dimethyl propanedioate;Methylmalonate;NSC 620046;Dimethyl Malonate (DMM);
EINECS:
203-597-8
Density:
1.156 g/cm³
Melting Point:
-62 °C(lit.)
Boiling Point:
177.1 °C at 760 mmHg
Flash Point:
90 °C
Appearance:
liquid
Hazard Symbols:
Xi
Risk Codes:
36/37/38
Safety Description:
26-36 Details

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Chemistry

IUPAC Name:dimethyl propanedioate
Molecular Formula: C₅H₈O₄
Molecular Weight:132.114620 g/mol
Appearance:Clear, colorless liquid
Melting Point:-62 °C(lit.)
Boiling Point:180-181 °C(lit.)
Flash Point:194 °F
Solubility:alcohol, ether and other organic solvents,slightly soluble in water
density:1.156 g/mL at 25 °C(lit.)
vapor density:>1 (vs air)
refractive index:n20/D 1.413(lit.)
Water Solubility:negligible
Merck:14,6096
BRN:774261
Synonyms of DIMETHYL MALONATE(108-59-8):
PROPANEDIOIC ACID DIMETHYL ESTER;Dimethyl ester of malonic acid;Dimethyl propanedioate;dimethyl1,3-propanedioate;dimethylpropanedioate;MALONIC ACID,BIS-METHYL ESTER;MALONIC ACID DIMETHYL ESTER;METHYL MALONATE
Categories of DIMETHYL MALONATE(108-59-8):
C2 to C5;Carbonyl Compounds;Esters

Uses

DIMETHYL MALONATE(108-59-8) is used as a common reagent for organic synthesis.

Toxicity Data With Reference

1.		skn-rbt 500 mg/24H		FCTXAV Food and Cosmetics Toxicology. 17 (1979),363.
2.		orl-rat LD50:5331 mg/kg		FCTXAV Food and Cosmetics Toxicology. 17 (1979),363.

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

Safety Information of DIMETHYL MALONATE(108-59-8):
Hazard Codes:Xi

Risk Statements:36/37/38
36/37/38:Irritating to eyes, respiratory system and skin
Safety Statements:26-36
26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
36:Wear suitable protective clothing
WGK Germany:1
RTECS:OO0950000
Hazard Note:Irritant
HS Code:29171910
Mildly toxic by ingestion. A skin irritant. Violent reaction with CH₃N₃ occurred with NaOCH₃ present. When heated to decomposition it emits acrid smoke and irritating fumes. See also ESTERS.

Specification

First Aid Measures of DIMETHYL MALONATE(108-59-8):
Ingestion:Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:Remove from exposure to fresh air immediately.
Skin:Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.
Eyes:Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids.

Storage of DIMETHYL MALONATE(108-59-8):
Store in a cool, dry place. Keep container closed when not in use.