Reported in EPA TSCA Inventory.

DOT Classification:  3; Label: Flammable Liquid

1. Introduction of Diallylamine

Diallylamine has the IUPAC name of N-prop-2-enylprop-2-en-1-amine. It is a kind of clear colourless to yellow liquid and belongs to the classes of Pharmaceutical Intermediates; Acyclic; Alkenes; Organic Building Blocks. And it should be stored in a cool, ventilated and dry place.

2. Properties of Diallylamine

Physical properties of Diallylamine are: (1)ACD/LogP: 1.11 ; (2)#H bond acceptors: 1; (3)#H bond donors: 1; (4)#Freely Rotating Bonds: 4; (5)Polar Surface Area: 12.03 Å²; (6)Index of Refraction: 1.432; (7)Molar Refractivity: 32.89 cm³; (8)Molar Volume: 126.5 cm³; (9)Polarizability: 13.03 ×10^-24cm³; (10)Surface Tension: 22.8 dyne/cm; (11)Density: 0.767 g/cm³; (12)Flash Point: 15.6 °C; (13)Enthalpy of Vaporization: 35.37 kJ/mol; (14)Boiling Point: 115.3 °C at 760 mmHg; (15)Vapour Pressure: 19.2 mmHg at 25°C.

3. Structure Descriptors of Diallylamine

You could convert the following datas into the molecular structure:
(1)SMILES: C=CCNCC=C
(2)InChI: InChI=1/C6H11N/c1-3-5-7-6-4-2/h3-4,7H,1-2,5-6H2
(3)InChIKey: DYUWTXWIYMHBQS-UHFFFAOYAO

4. Toxicity of Diallylamine

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Effect	Source
mammal (species unspecified)	LC50	inhalation	2100mg/m3 (2100mg/m3)		Toksikologiya Novykh Promyshlennykh Khimicheskikh Veshchestv. Toxicology of New Industrial Chemical Substances. For English translation, see TNICS*. Vol. 14, Pg. 80, 1975.
mammal (species unspecified)	LD50	unreported	350mg/kg (350mg/kg)		Toksikologiya Novykh Promyshlennykh Khimicheskikh Veshchestv. Toxicology of New Industrial Chemical Substances. For English translation, see TNICS*. Vol. 14, Pg. 80, 1975.
man	TCLo	inhalation	5ppm/5M (5ppm)	SENSE ORGANS AND SPECIAL SENSES: LACRIMATION: EYE LUNGS, THORAX, OR RESPIRATION: STRUCTURAL OR FUNCTIONAL CHANGE IN TRACHEA OR BRONCHI	Archives of Environmental Health. Vol. 1, Pg. 343, 1960.
mouse	LD50	intraperitoneal	187mg/kg (187mg/kg)	BEHAVIORAL: TREMOR GASTROINTESTINAL: OTHER CHANGES LUNGS, THORAX, OR RESPIRATION: RESPIRATORY DEPRESSION	Archives of Environmental Health. Vol. 1, Pg. 343, 1960.
mouse	LD50	oral	355mg/kg (355mg/kg)		"Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982Vol. -, Pg. 43, 1982.
rabbit	LD50	skin	280uL/kg (0.28mL/kg)		American Industrial Hygiene Association Journal. Vol. 23, Pg. 95, 1962.
rat	LC50	inhalation	795ppm/8H (795ppm)	SENSE ORGANS AND SPECIAL SENSES: OTHER CHANGES: OLFACTION SENSE ORGANS AND SPECIAL SENSES: LACRIMATION: EYE LUNGS, THORAX, OR RESPIRATION: DYSPNEA	Archives of Environmental Health. Vol. 1, Pg. 343, 1960.
rat	LD50	oral	578mg/kg (578mg/kg)	BEHAVIORAL: TREMOR LUNGS, THORAX, OR RESPIRATION: DYSPNEA GASTROINTESTINAL: OTHER CHANGES	Archives of Environmental Health. Vol. 1, Pg. 343, 1960.

5. Preparation of Diallylamine

Preparation of Diallylamine: it can be prepared by diallylcyanoamine through hydrolysis in the presence of sulfuric acid. This reaction should reflux for 6 hours, and the yield is about 80-88%. In addition, it also can be prepared by diallyl-carbamic acid 1-(3,5-dimethoxy-phenyl)-2-oxo-2-phenyl-ethyl ester. The other product is 5,7-dimethoxy-2-phenyl-benzofuran. This reaction will need reagent benzene with irradiation. The yield is about 56%. The equation as follows:

6. Uses of Diallylamine

Uses of Diallylamine: this chemical can be used as intermediates in organic synthesis. And it can react with acryloyl chloride to get diallylacrylamide. This reaction will need reagent Et₃N and solvent benzene. The reaction time is 30 minutes at reaction temperature of 0 °C. And the yield is about 99%.

7. Safety information of Diallylamine

Hazard Codes: F,T
Risk Statements: 11-20/22-24-34
Safety Statements: 16-26-36/37/39-45-28A
RIDADR UN: 2359 3/PG 2
WGK Germany: 3
RTECS: UC6650000
F: 2-10
HazardClass: 3
PackingGroup: II
Hazardous Substances Data: 124-02-7(Hazardous Substances Data)

When you are using this chemical, please be cautious about it as the following:
This chemical is highly flammable and can cause burns. In addition, it is toxic in contact with skin and harmful by inhalation and if swallowed. During using it, wear suitable protective clothing, gloves and eye/face protection. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. And in case of accident or if you feel unwell, seek medical advice immediately (show label where possible). What's more, you should keep away from sources of ignition.