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Basic information

  • Name:
  • Dichlorodimethylsilane

  • CAS No.:
  • 75-78-5

  • Molecular Structure:
  • Formula:
  • C2H6Cl2Si
  • Molecular Weight:
  • 129.06
  • Synonyms:
  • DCDMS;Dichlorodimethylsilicon;Dimethylsilane dichloride;Inerton AW-DMCS;KA 12;KA 22;LS 130;LS 130(silane);M 2 (silane);NSC 77070;Repel-Silane;Silane,dichlorodimethyl-;
  • EINECS:
  • 200-901-0
  • Density:
  • 1.075 g/cm3
  • Melting Point:
  • -76 °C
  • Boiling Point:
  • 69.999 °C at 760 mmHg
  • Flash Point:
  • -9 °C
  • Solubility:
  • reacts with water
  • Appearance:
  • Colorless to brown liquid
  • Hazard Symbols:
  • HarmfulXn, IrritantXi, FlammableF, DangerousN
  • Risk Codes:
  • 20-59-36/37/38-11-67-65-63-48/20-38-20/21-50/53
  • Safety Description:
  • 60-61-62-36/37-59 Details
  • Transport Information:
  • UN 2924 3/PG 2

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Chemistry

The Molecular Structure of Dichlorodimethylsilane (CAS NO.75-78-5):
 
Molecular Formula: C2H6Cl2Si
Molecular Weight: 129.06
EINECS: 200-901-0
Density: 1.06
Melting Point: -76 °C
Boiling Point: 70 °C
Flash Point: -9 °C
Appearance: Colourless liquid
Storage temp: Store at 0-5°C
Water Solubility: reacts
Sensitive: Moisture Sensitive 
IUPAC: dichloro(dimethyl)silane
Synonyms: Dichlorodimethyl-silan ; Dichlorodimethylsilicon ; Dimethyldichlorosilicane ; Dimethyl-dichlorsilan ; Dimethyl-dichlorsilan(czech) ; Dimethyldichlorsilane ; Dimethylsilanedichloride    
Stability: Stable. Reacts violently with water and alcohols. Highly flammable. Incompatible with strong oxidizing agents, water, alcohols, caustics, ammonia.
Product Categories: Chloro;Silicon Compounds;Organics;Dichlorosilanes;Dichlorosilanes (for Polysilanes);Functional Materials;Reagent for High-Performance Polymer Research;Si (Classes of Silicon Compounds);Si-Cl Compounds;Silicon Compounds (for Synthesis);Synthetic Organic Chemistry;Chloro Silanes

Uses

 Dichlorodimethylsilane (CAS NO.75-78-5) is used in ethchlorvynol assay.

Toxicity Data With Reference

1.    

skn-rbt 20 mg/24H MOD

    85JCAE    Prehled Prumyslove Toxikologie; Organicke Latky Marhold, J.,Prague, Czechoslovakia.: Avicenum,1986,1219.
2.    

eye-rbt 5 mg/24H SEV

    85JCAE    Prehled Prumyslove Toxikologie; Organicke Latky Marhold, J.,Prague, Czechoslovakia.: Avicenum,1986,1219.
3.    

orl-rat LD50:5660 µL/kg

    JACTDZ    Journal of the American College of Toxicology. 12 (1993),573.
4.    

ihl-rat LC50:930 ppm/4H

    85JCAE    Prehled Prumyslove Toxikologie; Organicke Latky Marhold, J.,Prague, Czechoslovakia.: Avicenum,1986,1219.
5.    

ipr-rat LDLo:10 mg/kg

    JIDHAN    Journal of Industrial Hygiene. 30 (1948),332.
6.    

ihl-mus LC50:300 mg/m3/2H

    TPKVAL    Toksikologiya Novykh Promyshlennykh Khimicheskikh Veshchestv. Toxicology of New Industrial Chemical Sciences. 3 (1961),23.

Consensus Reports

EPA Extremely Hazardous Substances List. Reported in EPA TSCA Inventory.

Safety Profile

Poison by ingestion and intraperitoneal routes. Moderately toxic by inhalation. A skin and severe eye irritant. Violent reaction on contact with water. When heated to decomposition it emits toxic fumes of Cl. See also CHLOROSILANES.
Hazard Codes: HarmfulXiHarmfulXnFlammableFDangerousN
Risk Statements: 20-59-36/37/38-11-67-65-63-48/20-38-20/21-50/53 
R20: Harmful by inhalation
R59: Dangerous to the ozone layer
R36/37/38: Irritating to eyes, respiratory system and skin
R11: Highly flammable
R67: Vapours may cause drowsiness and dizziness
R65: Harmful: may cause lung damage if swallowed
R63: Possible risk of harm to the unborn child
R38: Irritating to skin
R20/21: Harmful by inhalation and in contact with skin
R50/53: Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
Safety Statements: 60-61-62-36/37-59 
S60: This material and its container must be disposed of as hazardous waste
S61: Avoid release to the environment. Refer to special instructions / safety data sheets
S62: If swallowed, do not induce vomitting; seek medical advice immediately and show this container or label
S36/37: Wear suitable protective clothing and gloves
S59: Refer to manufacturer / supplier for information on recovery / recycling
RIDADR: UN 2924 3/PG 2
WGK Germany: 3
RTECS: VV3150000
F: 3-10-19-21
TSCA: Yes
HazardClass: 3
PackingGroup: II
HS Code: 29310095

Standards and Recommendations

DOT Classification:  3; Label: Flammable Liquid, Corrosive

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