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| Name |
Diisopropyl peroxydicarbonate |
EINECS | 203-317-4 |
| CAS No. | 105-64-6 | Density | 1.138 g/cm3 |
| PSA | 71.06000 | LogP | 2.02460 |
| Solubility | 30.5mg/L at 20℃ | Melting Point |
12 ºC |
| Formula | C8H14 O6 | Boiling Point | 208 °C at 760 mmHg |
| Molecular Weight | 206.196 | Flash Point | 79.1 °C |
| Transport Information | UN 2133/2134 | Appearance | Colorless, crystalline solid. |
| Safety | Moderately toxic by ingestion and skin contact. A severe eye irritant. Very dangerous fire hazard. Dangerously unstable above 10°C. An impact- and heat-sensitive explosive. Solutions may spontaneously explode (the hazard increases with concentration). Storage in sealed containers may be dangerous. Explodes on contact with amines or potassium iodide. May explode on contact with organic matter. When heated to decomposition it emits acrid smoke and fumes. See also PEROXIDES, ORGANIC. | Risk Codes | R36/37/38 |
| Molecular Structure |
|
Hazard Symbols | Spontaneous decomposition at room temperature releases flammable and corrosive products; dangerous fire hazard; explodes on heating. Store in open containers at low temperature with adequate ventilation. |
| Synonyms |
Peroxydicarbonicacid, bis(1-methylethyl) ester (9CI); Peroxydicarbonic acid, diisopropyl ester(6CI,8CI); Bisisopropyl peroxydicarbonate; Di-iso-propyl peroxydicarbonate;Diisopropyl percarbonate; Diisopropyl perdicarbonate; Diisopropylperoxydicarbonate; Diisopropyl peroxydiformate; IPP; Isopropylperoxydicarbonate; Luperox IPP; Perkadox IPP; Peroyl IPP |
Diisopropyl peroxydicarbonate Synthetic route
| Conditions | Yield |
|---|---|
| With sodium hydroxide; dihydrogen peroxide | 99% |
| With sodium hydroxide; dihydrogen peroxide In water at 15℃; Product distribution / selectivity; | 94% |
| With dihydrogen peroxide; potassium hydroxide In water at 5 - 50℃; for 0.0766667h; Flow reactor; | 74.7% |
| With sodium peroxide | |
| With sodium hydroxide; dihydrogen peroxide |
- 2564-83-2, 45842-10-2
2,2,6,6-Tetramethyl-1-piperidinyloxy free radical
- 105-64-6
diisopropyl peroxydicarbonate
- 105-06-6
1,4-Divinylbenzene
- 262616-04-6
2-(isopropyloxycarbonyloxy)-1-(2',2',6',6'-tetramethyl-1'-piperidinyloxy)-1-(4'-vinylphenyl)ethane
| Conditions | Yield |
|---|---|
| at 55℃; for 5h; | 76.1% |
- 132969-46-1
4-acetoxy-2,2,6,6-tetramethylpiperidine-1-oxyl
- 105-64-6
diisopropyl peroxydicarbonate
- 105-06-6
1,4-Divinylbenzene
| Conditions | Yield |
|---|---|
| at 0 - 55℃; for 5h; | 73% |
- 2564-83-2, 45842-10-2
2,2,6,6-Tetramethyl-1-piperidinyloxy free radical
- 105-64-6
diisopropyl peroxydicarbonate
- 108-57-6
1,3-divinylbenzene
| Conditions | Yield |
|---|---|
| 70.5% |
- 3225-26-1
4-(benzyloxycarbonyl)-2,2,6,6-tetramethylpiperidine-1-oxyl
- 105-64-6
diisopropyl peroxydicarbonate
- 105-06-6
1,4-Divinylbenzene
| Conditions | Yield |
|---|---|
| at 0 - 55℃; for 5h; | 62.1% |
- 105-64-6
diisopropyl peroxydicarbonate
- 142505-38-2
N-(4-chlorophenylmethylene)-2-methylthiobenzenamine
A
- 6265-91-4
2-(4-chlorophenyl)benzothiazole
B
- 104-88-1
4-chlorobenzaldehyde
C
- 142505-43-9
(2-aminophenyl)thiomethyl isopropyl carbonate
| Conditions | Yield |
|---|---|
| In benzene at 60℃; for 5h; | A 36% B 48% C 54% |
- 105-64-6
diisopropyl peroxydicarbonate
- 105-06-6
1,4-Divinylbenzene
- 2406-25-9, 44871-19-4
di-tert-butyl nitroxide
| Conditions | Yield |
|---|---|
| at 0 - 55℃; for 5h; | 53.2% |
- 105-64-6
diisopropyl peroxydicarbonate
- 19860-20-9
benzylidene-(2-methylsulfanyl-phenyl)-amine
A
- 883-93-2
2-Phenylbenzothiazole
B
- 100-52-7
benzaldehyde
C
- 142505-43-9
(2-aminophenyl)thiomethyl isopropyl carbonate
| Conditions | Yield |
|---|---|
| In benzene at 60℃; for 5h; | A 17% B 35% C 53% |
- 105-64-6
diisopropyl peroxydicarbonate
- 142505-40-6
N-(3-nitrophenylmethylene)-2-methylthiobenzenamine
A
- 22868-33-3
2-(3-nitrophenyl)benzothiazole
B
- 99-61-6
3-nitro-benzaldehyde
C
- 142505-43-9
(2-aminophenyl)thiomethyl isopropyl carbonate
D
- 142505-44-0
<(2-(3-nitrophenyl)methylenamino)phenyl>thiomethyl isopropyl carbonate
| Conditions | Yield |
|---|---|
| With 2,6-di-tert-butylphenol In benzene at 60℃; for 5h; | A 3% B 13% C 10% D 50% |
- 105-64-6
diisopropyl peroxydicarbonate
- 783-08-4
[4-(benzylideneamino)phenyl]methanol
A
- 128220-34-8
methyl 6-methoxy-2-phenylquinoline-4-carboxylate
B
- 85221-16-5
carbamic acid, (4-methoxyphenyl)-, 1-methylethyl ester
| Conditions | Yield |
|---|---|
| With acrylic acid methyl ester In benzene at 60℃; for 4h; | A 49% B 14% |
Diisopropyl peroxydicarbonate Chemical Properties
Chemical Name: Diisopropyl peroxydicarbonate
IUPAC NAME: Propan-2-yl propan-2-yloxycarbonyloxy carbonate
CAS No.: 105-64-6
EINECS: 203-317-4
RTECS Class: Primary Irritant
Molecular Formula: C8H14O6
Molecular Weight: 206.19 g/mol
Melting Point: 12°C
Density: 1.138 g/cm3
Flash Point: 79.1 °C
Boiling Point: 208 °C at 760 mmHg
Sensitive: Heat sensitive.
Following is the structure of Diisopropyl perdicarbonate (105-64-6):
The chemical synonymous of Diisopropyl perdicarbonate (105-64-6) are Diisopropyl peroxydicarbonate ; Bisisopropyl peroxydicarbonate ; Isopropyl peroxydicarbonate ; Isopropyl peroxycarbonate ; Peroxydicarbonic acid, diisopropyl ester ; Isopropylpercarbonate ; Diisopropylperoxydicarbonat ; Diisopropyl peroxydiformate
Diisopropyl peroxydicarbonate Toxicity Data With Reference
| 1. | eye-rbt 500 mg SEV | IHFCAY Industrial Hygiene Foundation of America, Chemical and Toxicological Series, Bulletin. 6 (1967),1. | ||
| 2. | orl-rat LD50:2140 mg/kg | IHFCAY Industrial Hygiene Foundation of America, Chemical and Toxicological Series, Bulletin. 6 (1967),1. | ||
| 3. | skn-rbt LD50:2025 mg/kg | BSPII* SPI Bulletin. (Society of the Plastics Industry, 250 Park Ave., New York, NY 10017) 1/75-19B . |
Diisopropyl peroxydicarbonate Consensus Reports
Reported in EPA TSCA Inventory.
Diisopropyl peroxydicarbonate Safety Profile
Moderately toxic by ingestion and skin contact. A severe eye irritant. Very dangerous fire hazard. Dangerously unstable above 10°C. An impact- and heat-sensitive explosive. Solutions may spontaneously explode (the hazard increases with concentration). Storage in sealed containers may be dangerous. Explodes on contact with amines or potassium iodide. May explode on contact with organic matter. When heated to decomposition it emits acrid smoke and fumes. See also PEROXIDES, ORGANIC.
Attention:
1. Storage: Keep in a cool, dry, dark location in a tightly sealed container or cylinder. Keep away from incompatible materials, ignition sources and untrained individuals. Secure and label area. Protect containers/cylinders from physical damage.
2. Handling: All chemicals should be considered hazardous. Avoid direct physical contact. Use appropriate, approved safety equipment. Untrained individuals should not handle this chemical or its container. Handling should occur in a chemical fume hood.
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