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Dimethylsilanediol

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Name

Dimethylsilanediol

EINECS 213-915-7
CAS No. 1066-42-8 Density 0.999 g/cm3
PSA 40.46000 LogP -0.32720
Solubility N/A Melting Point 101℃
Formula C2H8O2Si Boiling Point 122.193 °C at 760 mmHg
Molecular Weight 92.1698 Flash Point 27.701 °C
Transport Information N/A Appearance N/A
Safety Risk Codes N/A
Molecular Structure Molecular Structure of 1066-42-8 (dimethylsilanediol) Hazard Symbols N/A
Synonyms

Silanediol,dimethyl- (6CI,7CI,8CI,9CI);Dihydroxydimethylsilane;Dimethyldihydroxysilane;

Article Data 21

Dimethylsilanediol Synthetic route

50870-64-9

dibenzyloxydimethylsilane

1066-42-8

dimethylsilanediol

Conditions
ConditionsYield
With palladium-platinum; hydrogen; aniline at 20℃; for 2h;98%
78-62-6

diethoxy dimethylsilane

1066-42-8

dimethylsilanediol

Conditions
ConditionsYield
With H2O In water byproducts: C2H5OH; (CH3)2Si(OC2H5)2 (0.5 mol) and H2O (2 mol) at room temp. for 2 days (shaking);; evapn. of H2O and ethanol at 25°C;;92%
With water
50870-64-9

dibenzyloxydimethylsilane

A

1066-42-8

dimethylsilanediol

B

1118-15-6

tetramethyl-1,3-disiloxanediol

Conditions
ConditionsYield
With palladium-platinum; hydrogen; aniline In N,N-dimethyl acetamide at 20℃; for 2h; Concentration;A 88%
B 6%
1112-39-6

dimethyldimethoxysilan

1066-42-8

dimethylsilanediol

Conditions
ConditionsYield
With water
With water; acetic anhydride at 20 - 40℃; for 0.25h; Hydrolysis;
With H2O In water byproducts: CH3OH; heating of (CH3)2Si(OCH3)2 and H2O;; evapn. of H2O and CH3OH at room temp. by passing over of dry N2; washing of the residue with hot n-hexane; residue;;65-78
With H2O In water byproducts: CH3OH; heating of (CH3)2Si(OCH3)2 and H2O;; evapn. of H2O and CH3OH at room temp. by passing over of dry N2; washing of the residue with hot n-hexane; residue;;65-78
75-78-5

dimethylsilicon dichloride

A

1066-42-8

dimethylsilanediol

B

67-64-1

acetone

Conditions
ConditionsYield
With diethyl ether; water; aniline
1118-15-6

tetramethyl-1,3-disiloxanediol

A

1066-42-8

dimethylsilanediol

B

3663-50-1

1,1,3,3,5,5-Hexamethyltrisiloxane-1,5-diol

Conditions
ConditionsYield
With trifluorormethanesulfonic acid; water In 1,4-dioxane at 35℃; Rate constant;
65007-35-4

ethoxydimethylsilanol

1066-42-8

dimethylsilanediol

Conditions
ConditionsYield
With hydrogenchloride In 1,4-dioxane; water at 30℃; Rate constant;
75-78-5

dimethylsilicon dichloride

1066-42-8

dimethylsilanediol

Conditions
ConditionsYield
With water
With water; triethylamine In diethyl ether; acetone at 0℃; for 0.5h;
With hydrogenchloride; water at 35℃; under 1500.15 Torr;
1009-93-4

2,2,4,4,6,6-hexamethylcyclotrisilazane

A

1066-42-8

dimethylsilanediol

B

1118-15-6

tetramethyl-1,3-disiloxanediol

Conditions
ConditionsYield
With potassium dichromate; sulfuric acid; silver sulfate In water for 2h; Mechanism; Heating; other organosilicon compounds, chemical oxygen demand value, oxidizability, glass beads presence;
1118-15-6

tetramethyl-1,3-disiloxanediol

A

1066-42-8

dimethylsilanediol

B

3663-50-1

1,1,3,3,5,5-Hexamethyltrisiloxane-1,5-diol

C

556-67-2

octamethylcyclotetrasiloxane

Conditions
ConditionsYield
With sulfuric acid In phosphate buffer for 24h; pH=6; Equilibrium constant; Kinetics; Further Variations:; pH-values; Hydrolysis;

Dimethylsilanediol Specification

The Dimethylsilanediol, with the CAS registry number 1066-42-8, is also known as Dimethyldihydroxysilane. Its EINECS number is 213-915-7. This chemical's molecular formula is C2H8O2Si and molecular weight is 92.17. What's more, its systematic name is Methyl [3-(bromomethyl)phenyl]acetate.

Physical properties of Dimethylsilanediol are: (1)ACD/LogP: 0.493; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): 0.49; (4)ACD/LogD (pH 7.4): 0.49; (5)ACD/BCF (pH 5.5): 1.40; (6)ACD/BCF (pH 7.4): 1.40; (7)ACD/KOC (pH 5.5): 44.20; (8)ACD/KOC (pH 7.4): 44.20; (9)#H bond acceptors: 2; (10)#H bond donors: 2; (11)#Freely Rotating Bonds: 2; (12)Polar Surface Area: 40.46 Å2; (13)Index of Refraction: 1.415; (14)Molar Refractivity: 23.102 cm3; (15)Molar Volume: 92.298 cm3; (16)Polarizability: 9.158×10-24cm3; (17)Surface Tension: 24.0 dyne/cm; (18)Density: 0.999 g/cm3; (19)Flash Point: 27.701 °C; (20)Enthalpy of Vaporization: 41.981 kJ/mol; (21)Boiling Point: 122.193 °C at 760 mmHg; (22)Vapour Pressure: 6.7 mmHg at 25°C.

You can still convert the following datas into molecular structure:
(1)SMILES: O[Si](O)(C)C
(2)Std. InChI: InChI=1S/C2H8O2Si/c1-5(2,3)4/h3-4H,1-2H3
(3)Std. InChIKey: XCLIHDJZGPCUBT-UHFFFAOYSA-N  

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