ETHYL FLUOROACETATE (459-72-3),ETHYL FLUOROACETATE (459-72-3) Manufacturers & Suppliers,Synthesis,MSDS

Basic information

Name:
Aceticacid, 2-fluoro-, ethyl ester
Superlist Name:
Ethyl fluoroacetate
CAS No.:
459-72-3
Molecular Structure:
Formula:
C₄H₇FO₂
Molecular Weight:
106.11
Synonyms:
Aceticacid, fluoro-, ethyl ester (6CI,7CI,8CI,9CI);Ethylmonofluoroacetate;Fluoroacetic acid ethyl ester;Monofluoroacetic acid ethylester;NSC 133459;
EINECS:
207-297-8
Density:
1.025 g/cm³
Boiling Point:
118 °C at 760 mmHg
Flash Point:
30 °C
Solubility:
decomposes in water
Appearance:
clear colorless liquid
Hazard Symbols:
T, T+
Risk Codes:
10-26/27/28
Safety Description:
13-36/37/39-45-28A-16 Details
Transport Information:
UN 2929 6.1/PG 1

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Chemistry

IUPAC Name:ethyl 2-fluoroacetate
Molecular Formula:C₄H₇FO₂
Molecular Weight:106.095583 g/mol
Appearance:Liquid
Boiling Point:119.3 °C753 mm Hg(lit.)
Flash Point:86 °F
density:1.098 g/mL at 25 °C(lit.)
refractive index:n20/D 1.375(lit.)
storage temp.:Flammables area
Water Solubility:DECOMPOSES
Merck:4167
Synonyms of ETHYL FLUOROACETATE(459-72-3):
ETHYL FLUOROACETATE;ETHYL MONOFLUOROACETATE;FLUOROACETIC ACID ETHYL ESTER;Aceticacid,fluoro-,ethylester;Ethylester kyseliny fluoroctove;ethylesterkyselinyfluoroctove;Fluoracetic acid ethyl ester;fluoro-aceticaciethylester
Categories of ETHYL FLUOROACETATE(459-72-3):
Fluoro-Aliphatics ;Fluorinated Building Blocks;Fluorinating Reagents & Building Blocks for Fluorinated Biochemical Compounds;Synthetic Organic Chemistry;C2 to C5;Carbonyl Compounds;Esters

Uses

ETHYL FLUOROACETATE(459-72-3) is used as pharmaceutical intermediates for the synthesis of 5 - fluorouracil, fluorocytosine.

Toxicity Data With Reference

ipr-mus LD50:19 mg/kg

11FYAN Fluorine Chemistry, Volume III. Biological Effects of Organic Fluorides. 3 (1963),59.

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

Safety Information of ETHYL FLUOROACETATE(459-72-3):
Hazard Codes:T+,T

Risk Statements:10-26/27/28
10:Flammable
26/27/28:Very Toxic by inhalation, in contact with skin and if swallowed
Safety Statements:13-36/37/39-45-28A-16
13:Keep away from food, drink and animal feeding stuffs
36/37/39:Wear suitable protective clothing, gloves and eye/face protection
45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
28:After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer)
16:Keep away from sources of ignition - No smoking
RIDADR:UN 2929 6.1/PG 1
WGK Germany:3
RTECS:AH7175000
F:21
Hazard Note:Toxic
HazardClass:6.1(a)
PackingGroup:II
HS Code:29159080
Poison by intraperitoneal route. When heated to decomposition it emits toxic fumes of F⁻. See also FLUORIDES.

Specification

First Aid Measures of ETHYL FLUOROACETATE(459-72-3):
Ingestion:Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. DO NOT use mouth-to-mouth respiration.
Skin:Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Eyes:Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.

Storage of ETHYL FLUOROACETATE(459-72-3):
Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Flammables-area.