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Name	Ethyl propenyl ether	EINECS	213-176-0
CAS No.	928-55-2	Density	0.775 g/cm³
PSA	9.23000	LogP	1.55650
Solubility	soluble in water	Melting Point	-140°C (estimate)
Formula	C₅H₁₀O	Boiling Point	68.2 °C at 760 mmHg
Molecular Weight	86.1338	Flash Point	-2 °F
Transport Information	UN 3271 3/PG 2	Appearance	clear colorless to light yellow liquid
Safety	16-26-36/37/39-37/39	Risk Codes	11-36/37/38
Molecular Structure		Hazard Symbols	F,Xi
Synonyms	Ether,ethyl propenyl (6CI,7CI,8CI);1-Ethoxy-1-propene;1-Ethoxypropene;Ethyl1-propenyl ether;NSC 6107;Ether, ethyl propenyl;	Article Data	21

Ethyl propenyl ether Synthetic route

: 557-31-3
3-ethoxyprop-1-ene

: 928-55-2
ethyl 1-propenyl ether

Conditions

Conditions	Yield
With diiron nonacarbonyl In benzene at 40 - 50℃; for 2.5h;	90%
With triiron dodecarbonyl at 25 - 30℃; for 1h; Irradiation;	85%
With potassium tert-butylate In dimethyl sulfoxide at 70℃; for 0.833333h; Inert atmosphere;	70%
(PMe3)2Rh(D2O)2*BF4 In water-d2 at 25℃; for 0.5h;	95 % Spectr.

: 4744-08-5
1,1-diethoxypropane

: 928-55-2
ethyl 1-propenyl ether

Conditions

Conditions	Yield
2-ethyl-N-(2-ethylhexyl)-1-hexanamine; toluene-4-sulfonic acid	77.5%
With quinoline; phosphorus pentoxide distillation at a bath temp. 150 deg C;	75%
With quinoline; phosphorus pentoxide vermutlich entsteht als Gemisch von cis- und trans-Form;
With sodium hydrogen sulfate vermutlich entsteht als Gemisch von cis- und trans-Form;
With silver-asbestos at 280℃; vermutlich entsteht als Gemisch von cis- und trans-Form;

: 23981-30-8
3-ethoxy-2-methyl-acrylic acid

A: 928-55-2
ethyl 1-propenyl ether

B: 15719-64-9, 15719-76-3, 97762-63-5
methylammonium carbonate

β-ethoxymethacrylic acid: β-ethoxymethacrylic acid

: 928-55-2
ethyl 1-propenyl ether

Conditions

Conditions	Yield
bei vorsichtigem Kochen;

: 187737-37-7
propene

: 109-92-2
ethyl vinyl ether

: 928-55-2
ethyl 1-propenyl ether

Conditions

Conditions	Yield
With tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride In benzene-d6 at 60℃; for 1h;

: 557-31-3
3-ethoxyprop-1-ene

: 998-30-1
Triethoxysilane

A: 628-32-0
ethylpropylether

B: 928-55-2
ethyl 1-propenyl ether

C: 81518-55-0
triethoxy(3-ethoxypropyl)silane

Conditions

Conditions	Yield
With platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex In 5,5-dimethyl-1,3-cyclohexadiene; diethylene glycol dimethyl ether at 70℃; for 12h; Inert atmosphere;

: 557-31-3
3-ethoxyprop-1-ene

: 5700-39-0
tris(2-methoxyethoxy)silane

A: 628-32-0
ethylpropylether

B: 928-55-2
ethyl 1-propenyl ether

C: C14H32O7Si

Conditions

Conditions	Yield
With platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex In 5,5-dimethyl-1,3-cyclohexadiene; toluene at 70℃; for 12h; Inert atmosphere;

: 928-55-2
ethyl 1-propenyl ether

: 1516-56-9
azidoformiate de methyle

: [1-Ethoxy-prop-(Z)-ylidene]-carbamic acid methyl ester

Conditions

Conditions	Yield
In benzene at 80℃; for 24h;	100%

: 694479-85-1
5-iodo-6-methyl-N-[4-(methylsulfonyl)benzyl]-2-oxo-1-[3-(trifluoromethyl)phenyl]-1,2-dihydropyridine-3-carboxamide

: 928-55-2
ethyl 1-propenyl ether

: 6-methyl-N-[4-(methylsulfonyl)benzyl]-2-oxo-5-propionyl-1-[3-(trifluoromethyl)phenyl]-1,2-dihydropyridine-3-carboxamide

Conditions

Conditions	Yield
Stage #1: 5-iodo-6-methyl-N-[4-(methylsulfonyl)benzyl]-2-oxo-1-[3-(trifluoromethyl)phenyl]-1,2-dihydropyridine-3-carboxamide; ethyl 1-propenyl ether With triethylamine; bis[1,2-bis(diphenylphosphino)ethane]palladium(0) In DMF (N,N-dimethyl-formamide) at 100℃; Stage #2: With hydrogenchloride; water In DMF (N,N-dimethyl-formamide) for 1.5h;	99%
Stage #1: 5-iodo-6-methyl-N-[4-(methylsulfonyl)benzyl]-2-oxo-1-[3-(trifluoromethyl)phenyl]-1,2-dihydropyridine-3-carboxamide; ethyl 1-propenyl ether With triethylamine; bis[1,2-bis(diphenylphosphino)ethane]palladium(0) In DMF (N,N-dimethyl-formamide) at 100℃; Stage #2: With hydrogenchloride; water In DMF (N,N-dimethyl-formamide) for 1.5h;	99%

: 928-55-2
ethyl 1-propenyl ether

: 525-06-4
diphenyl ketene

: 32929-60-5, 32949-69-2, 55701-86-5
3-ethoxy-4-methyl-2,2-diphenylcyclobutanone

Conditions

Conditions	Yield
In diethyl ether at 20℃;	99%

Ethyl propenyl ether Chemical Properties

Molecular structure of Ether, ethyl propenyl (CAS NO.928-55-2) is:

Product Name: Ether, ethyl propenyl
CAS Registry Number: 928-55-2
IUPAC Name: (Z)-1-ethoxyprop-1-ene
Molecular Weight: 86.1323 [g/mol]
Molecular Formula: C₅H₁₀O
XLogP3-AA: 1.4
H-Bond Donor: 0
H-Bond Acceptor: 1
EINECS: 213-176-0
Refractive index: n20/D 1.398(lit.)
Storage temp.: Flammables area
Water Solubility: soluble
Surface Tension: 21 dyne/cm
Density: 0.775 g/cm³
Flash Point: -2 °F
Enthalpy of Vaporization: 29.71 kJ/mol
Boiling Point: 68.2 °C at 760 mmHg
Vapour Pressure: 153 mmHg at 25°C
Classification Code: Skin / Eye Irritant

Ethyl propenyl ether Uses

Ether, ethyl propenyl (CAS NO.928-55-2) is used in organic synthesis.It is also used in coating, adhesive, additives, plasticizer, etc.

Ethyl propenyl ether Toxicity Data With Reference

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Source
rabbit	LD50	skin	3970uL/kg (3.97mL/kg)	Toxicology and Applied Pharmacology. Vol. 28, Pg. 313, 1974.
rat	LCLo	inhalation	8000ppm/4H (8000ppm)	Toxicology and Applied Pharmacology. Vol. 28, Pg. 313, 1974.
rat	LD50	oral	4660uL/kg (4.66mL/kg)	Toxicology and Applied Pharmacology. Vol. 28, Pg. 313, 1974.

Ethyl propenyl ether Safety Profile

Hazard Codes: F, Irritant Xi
Risk Statements: 11-36/37/38
R11:Highly flammable.
R36/37/38:Irritating to eyes, respiratory system and skin.
Safety Statements: 16-26-36/37/39-37/39
S16:Keep away from sources of ignition.
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection.
S37/39:Wear suitable gloves and eye/face protection.
RIDADR: UN 3271 3/PG 2
WGK Germany: 3
RTECS: KO0525000
HazardClass: 3
PackingGroup: II

Ethyl propenyl ether Specification

Ether, ethyl propenyl , its cas register number is 928-55-2. It also can be called 1-Ethoxy-1-propene ; 1-Ethoxypropene ; Ethyl 1-propenyl ether ; Ethyl propenyl ether ; Propenyl ethyl ether ; 1-Propene, 1-ethoxy- .It is a clear colorless to light yellow liquid.

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