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Fenpropathrin

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Fenpropathrin

EINECS 254-485-0
CAS No. 39515-41-8 Density 1.128 g/cm3
PSA 59.32000 LogP 5.26898
Solubility 14.24ug/L(temperature not stated) Melting Point 50 - 51oC
Formula C22H23NO3 Boiling Point 448.2 °C at 760 mmHg
Molecular Weight 349.43 Flash Point 195.5 °C
Transport Information UN 2811 6.1/PG 2 Appearance Yellowish to brown liquid or solid
Safety 28-36/37-38-45-60-61 Risk Codes 21-25-26-50/53
Molecular Structure Molecular Structure of 39515-41-8 (Fenpropathrin) Hazard Symbols VeryT+, DangerousN
Synonyms

2,2,3,3-Tetramethylcyclopropanecarboxylic acid cyano(3-phenoxyphenyl)methylester;Danimen;Danitol;Danitol 10EC;Danitol Fiori;Fenpropanate;Kilumal;Meiothrin;Meothrin;Miothrin;Rody;S 3206;SD 41706;Smash;WL 41706;XE 938;a-Cyano-3-phenoxybenzyl 2,2,3,3-tetramethylcyclopropanecarboxylate;

Article Data 14

Fenpropathrin Chemical Properties

IUPAC Name: [Cyano-(3-phenoxyphenyl)methyl] 2,2,3,3-tetramethylcyclopropane-1-carboxylate
Synonyms: (S)-Fenpropathrin ; .Alpha.-Cyano-3-phenoxybenzyl 2,2,3,3-tetramethyl-1-cyclopropanecarboxylate ; 2,2,3,3-Tetramethylcyclopropane Carboxylic Acid Cyano(3-phenoxyphenyl)methyl Ester ; 2,2,3,3-Tétraméthylcyclopropanecarboxylate de cyano(3-phénoxyphényl)méthyle ; A-Cyano-3-phenoxybenzyl 2,2,3,3-Tetramethylcyclopropanecarboxylate ; Cyan(3-phenoxyphenyl)methyl-2,2,3,3-tetramethylcyclopropancarboxylat ; Cyano(3-phenoxyphenyl)methyl 2,2,3,3-tetramethylcyclopropanecarboxylate ; Cyano(3-phenoxyphenyl)methyl 2,2,3,3-tetramethylcyclopropanecarboxylate (9CI)
Product Categories: AcaricidesPesticides&Metabolites;Alpha sort;E-GAlphabetic;F;FA - FLPesticides;Insecticides;Pesticides;Pesticides&Metabolites;Pyrethroids;AcaricidesAlphabetic
Molecular Structure of Fenpropathrin (CAS NO.39515-41-8) :
Molecular Formula of Fenpropathrin (CAS NO.39515-41-8) : C22H23NO3
Molecular Weight of Fenpropathrin (CAS NO.39515-41-8) : 349.43
CAS NO: 39515-41-8
EINECS : 254-485-0
Mol File: 39515-41-8.mol
Index of Refraction: 1.551
Surface Tension: 42.5 dyne/cm
Density: 1.128 g/cm3
Flash Point: 195.5 °C
Enthalpy of Vaporization: 70.66 kJ/mol
Boiling Point: 448.2 °C at 760 mmHg
Vapour Pressure: 3.17E-08 mmHg at 25°C

Fenpropathrin Uses

 Fenpropathrin (CAS NO.39515-41-8) is broad-spectrum, highly efficient killing pyrethrins insecticide, acaricide, with contact and repellent effects, can prevent Hemiptera and mite pests of vegetables, cotton, cereal crops, Lepidoptera, using concentrations of 50 -- 200ppm

Fenpropathrin Production

Preparation Products Fenpropathrin+Phoxim,E.C.
Raw materials Thionyl chloride-->Sodium nitrite-->Azabenzene-->Xylene-->Sodium cyanide-->Phenol-->Heptane-->3-Phenoxy-benzaldehyde-->Permethric acid-->olefine ketone-->diazoacetic acid-->2,2,3,3-TETRAMETHYLCYCLOPROPANECARBOXYLIC ACID-->Cyclobutanone-->Cyclopropanecarboxylic acid chloride
2,2,3,3 - Tetramethyl-cyclopropane chloride in N-Heptane, water and phase transfer catalyst, react with the M-Phenoxy benzaldehyde, Sodium cyanide reaction, obtaining  Fenpropathrin (CAS NO.39515-41-8). Consumption of raw materials fixed: Ju acid 110kg / t, ether aldehyde 800kg / t.

Fenpropathrin Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
chicken LD50 unreported 1gm/kg (1000mg/kg)   Defense des Vegetaux. Vol. 37, Pg. 59, 1983.
dog LD50 oral > 1gm/kg (1000mg/kg)   Defense des Vegetaux. Vol. 37, Pg. 59, 1983.
duck LD50 oral 1089mg/kg (1089mg/kg)   Pesticide Manual. Vol. 9, Pg. 377, 1991.
mouse LD50 intraperitoneal 210mg/kg (210mg/kg)   Japan Pesticide Information. Vol. (38), Pg. 21, 1981.
mouse LD50 oral 58mg/kg (58mg/kg)   Japan Pesticide Information. Vol. (38), Pg. 21, 1981.
mouse LD50 skin 740mg/kg (740mg/kg)   Japan Pesticide Information. Vol. (38), Pg. 21, 1981.
mouse LD50 subcutaneous 900mg/kg (900mg/kg)   Japan Pesticide Information. Vol. (38), Pg. 21, 1981.
rabbit LD50 oral 510mg/kg (510mg/kg)   Japan Pesticide Information. Vol. (38), Pg. 21, 1981.
rabbit LD50 skin > 2gm/kg (2000mg/kg)   Farm Chemicals Handbook. Vol. -, Pg. C137, 1991.
rat LC50 inhalation > 19070gm/m3/4 (19070000mg/m3) BRAIN AND COVERINGS: OTHER DEGENERATIVE CHANGES

BEHAVIORAL: TREMOR

LIVER: OTHER CHANGES
National Technical Information Service. Vol. OTS0535837,
rat LD50 intraperitoneal 180mg/kg (180mg/kg)   Japan Pesticide Information. Vol. (38), Pg. 21, 1981.
rat LD50 oral 18mg/kg (18mg/kg)   Pesticide Science. Vol. 8, Pg. 579, 1977.
rat LD50 skin 870mg/kg (870mg/kg)   Pesticide Manual. Vol. 9, Pg. 377, 1991.
rat LD50 subcutaneous 900mg/kg (900mg/kg)   Japan Pesticide Information. Vol. (38), Pg. 21, 1981.
rat LDLo intravenous 2500ug/kg (2.5mg/kg) BEHAVIORAL: TREMOR

BEHAVIORAL: REGIDITY

BEHAVIORAL: AGGRESSION
Archives of Toxicology. Vol. 45, Pg. 325, 1980.

Fenpropathrin Safety Profile

Hazard Codes VeryT+,DangerousN
Risk Statements 21-25-26-50/53
R21:Harmful in contact with skin. 
R25 :Toxic if swallowed. 
R26:Very toxic by inhalation.
Safety Statements 28-36/37-38-45-60-61
S28:After contact with skin, wash immediately with plenty of soap-suds. 
S36/37:Wear suitable protective clothing and gloves. 
S38:In case of insufficient ventilation, wear suitable respiratory equipment. 
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) 
S60:This material and its container must be disposed of as hazardous waste. 
S61:Avoid release to the environment. Refer to special instructions / safety data sheets.
RIDADR UN 2811 6.1/PG 2
RTECS GZ2090000

Fenpropathrin Specification

1.General Description :Yellowish to brown liquid or solid, depending on purity and temperature. Used as an acaricide and insecticide.
2.Air & Water Reactions: In water, solubility is 14 ppm. Slowly oxidized in air. Decomposed by alkaline solutions.
3.Reactivity Profile: A pyrethroid. Fenpropathrin is an ester and nitrile. Esters react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides. Nitriles may polymerize in the presence of metals and some metal compounds. They are incompatible with acids; mixing nitriles with strong oxidizing acids can lead to extremely violent reactions. Nitriles are generally incompatible with other oxidizing agents such as peroxides and epoxides. The combination of bases and nitriles can produce hydrogen cyanide. Nitriles are hydrolyzed in both aqueous acid and base to give carboxylic acids (or salts of carboxylic acids). These reactions generate heat. Peroxides convert nitriles to amides. Nitriles can react vigorously with reducing agents. Acetonitrile and propionitrile are soluble in water, but nitriles higher than propionitrile have low aqueous solubility. They are also insoluble in aqueous acids.

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