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Fluorapatite

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Name

Fluorapatite

EINECS N/A
CAS No. 1306-05-4 Density 3.205 g/cm3
PSA 288.18000 LogP -1.83800
Solubility Soluble in water and hydrochloric acid. Melting Point N/A
Formula Ca10F2O4P Boiling Point N/A
Molecular Weight 533.77 Flash Point N/A
Transport Information N/A Appearance N/A
Safety When heated to decomposition it emits very toxic fumes of F and POx. See also FLUORIDES and PHOSPHATES. Risk Codes N/A
Molecular Structure Molecular Structure of 1306-05-4 (Fluorapatite (Ca5F(PO4)3)) Hazard Symbols N/A
Synonyms

Fluorapatite (Ca5F(PO4)3);fluorapatite

 

Fluorapatite Chemical Properties

Chemistry informtion about Fluorapatite (CAS NO.1306-05-4) is:
IUPAC Name: Dicalcium Fluoride Phosphate
Synonyms: Fluorapatite (Ca5F(PO4)3) ; Fluorapatite
MF: Ca5FO12P3
EINECS: 215-144-1

Fluorapatite Uses

Fluorapatite (CAS NO.1306-05-4) can be used as a precursor for the production of phosphorus. It can be reduced by carbon in the presence of quartz:
4 Ca5(PO4)3F + 21 SiO2 + 30 C → 20 CaSiO3 + 30 CO + SiF4 + 6 P2
Upon cooling, white phosphorus (P4) is generated:
2 P2P4

Fluorapatite Safety Profile

When heated to decomposition it emits very toxic fumes of F and POx. See also FLUORIDES and PHOSPHATES.

Fluorapatite Standards and Recommendations

OSHA PEL: TWA 2.5 mg(F)/m3
ACGIH TLV: TWA 2.5 mg(F)/m3; BEI: 3 mg/g creatinine of fluorides in urine prior to shift; 10 mg/g creatinine of fluorides in urine at end of shift.
NIOSH REL: (Inorganic Fluorides) TWA 2.5 mg(F)/m3

Fluorapatite Analytical Methods

Fluorapatite (CAS NO.1306-05-4), can be synthesized in a two step process. First, calcium phosphate is generated by combining calcium and phosphate salts at neutral pH.This material then reacts further with fluoride sources (often sodium monofluorophosphate or calcium fluoride (CaF2)) to give the mineral. This reaction is integral in the global phosphorus cycle.
3 Ca2+ + 2 PO3−4Ca3(PO4)2
3 Ca3(PO4)2 + CaF2 → 2 Ca5(PO4)3F

Fluorapatite Specification

Fluorapatite (CAS NO.1306-05-4), often with the alternate spelling of fluoroapatite, is a mineral with the formula Ca5F(PO4)3 (calcium halophosphate). Fluorapatite is a hard crystalline solid. Although samples can have various color (green, brown, blue, violet, or colorless), the pure mineral is colorless as expected for a material lacking transition metals. It is an important constituent of tooth enamel. Fluorapatite is the most common phosphate mineral. It occurs widely as an accessory mineral in igneous rocks and in calcium rich metamorphic rocks. It commonly occurs as a detrital or diagenic mineral in sedimentary rocks and is an essential component of phosphorite ore deposits. It occurs as a residual mineral in lateritic soils.

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