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Formylhydrazine

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Name

Formylhydrazine

EINECS 210-867-9
CAS No. 624-84-0 Density 1.094 g/cm3
PSA 55.12000 LogP 0.33320
Solubility Soluble in water Melting Point 52-57 °C(lit.)
Formula CH4N2O Boiling Point 129.7 °C at 760 mmHg
Molecular Weight 60.0556 Flash Point 32.2 °C
Transport Information N/A Appearance white shiny crystalline flakes
Safety 26-36-36/37/39 Risk Codes 36/37/38-20/21/22
Molecular Structure Molecular Structure of 624-84-0 (Formylhydrazine) Hazard Symbols HarmfulXn,IrritantXi
Synonyms

Formicacid, hydrazide (7CI,8CI);Hydrazine, formyl- (6CI);Carbazaldehyde;Formic hydrazide;Formohydrazide;Formylhydrazide;Monoformylhydrazine;N-Formylhydrazine;NSC 72391;

Article Data 32

Formylhydrazine Chemical Properties

IUPAC Name: Formohydrazide
The MF of Formohydrazide (CAS NO.624-84-0) is CH4N2O.

                          
The MW of Formohydrazide (CAS NO.624-84-0) is 60.06.
Synonyms of Formohydrazide (CAS NO.624-84-0): Formic hydrazide ; Hydrazine, formyl- ; Formic acid hydrazide ; Carbazaldehyde ; Formhydrazid
Apperance: white shiny crystalline flakes
Index of Refraction: 1.424 
EINECS: 210-867-9
Density: 1.094 g/ml 
Flash Point: 32.2 °C 
Boiling Point: 129.7 °C
Melting Point: 54-56 °C
Storage temp: 2-8 °C
Water Solubility: Soluble
Sensitive: Hygroscopic
BRN: 635759

Formylhydrazine Uses

  Formohydrazide (CAS NO.624-84-0) is used in organic synthesis.

Formylhydrazine Production

Be careful to join the 85% hydrazine hydrate and 95% ethyl alcohol solution,stirring 10min. When the relaxation response,making the reaction solution refluxed 18h, vacuuming steam out of most of the water and ethanol.It was tilting crude syrup, and further refined to be finished formyl hydrazine.

Formylhydrazine Toxicity Data With Reference

1.    

scu-rat LD50:120 mg/kg

    ARZNAD    Arzneimittel-Forschung. Drug Research. 18 (1968),645.
2.    

ipr-mus LD50:65 mg/kg

    JMPCAS    Journal of Medicinal and Pharmaceutical Chemistry. 4 (1961),259.

Formylhydrazine Consensus Reports

Reported in EPA TSCA Inventory.

Formylhydrazine Safety Profile

Poison by intraperitoneal and subcutaneous routes. Questionable carcinogen with experimental neoplastigenic data. When heated to decomposition it emits toxic fumes of NOx. See also HYDRAZINE.Safety information of Formohydrazide (CAS NO.624-84-0):
Hazard Codes  IrritantXi,Xn
Risk Statements 
36/37/38 Irritating to eyes, respiratory system and skin
20/21/22 Harmful by inhalation, in contact with skin and if swallowed
Safety Statements 
26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
36/37/39 Wear suitable protective clothing, gloves and eye/face protection
WGK Germany  3
RTECS  LQ8615000
F  3-8-10

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