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Basic information

  • Name:
  • Fosetyl-aluminium

  • Superlist Name:
  • Fosetyl-aluminum
  • CAS No.:
  • 39148-24-8

  • Molecular Structure:
  • Formula:
  • C6H18AlO9P3
  • Molecular Weight:
  • 354.13
  • Synonyms:
  • Phosphonicacid, monoethyl ester, aluminum salt (9CI);Aliette;Aliette 80WG;Aluminumtris(O-ethylphosphonate);Aluminum tris(ethyl phosphite);Chipco AlietteSignature;EXP 1659;Efal;Efal 50;Efosite Al;Ephal;Fosethyl Al;Fosetyl Al;Fosetyl aluminum;LS 74-783;Phosethyl Al;Yilinlu;
  • EINECS:
  • 254-320-2
  • Hazard Symbols:
  • IrritantXi
  • Risk Codes:
  • 41
  • Safety Description:
  • 26-39 Details

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Chemistry

Molecular Structure of Fosetyl-aluminum (CAS NO.39148-24-8):

IUPAC Name: aluminum ethoxy-oxido-oxophosphanium 
Empirical Formula: C6H18AlO9P3
Molecular Weight: 354.1045
H bond acceptors: 9
H bond donors: 3
Freely Rotating Bonds: 6
Polar Surface Area: 177.51 Å2
EINECS: 254-320-2
Storage temp: 0-6°C
InChI
InChI=1/3C2H7O3P.Al/c3*1-2-5-6(3)4;/h3*6H,2H2,1H3,(H,3,4);/q;;;+3/p-3
Smiles
O(P(=O)[O-])CC.O(P(=O)[O-])CC.O(P(=O)[O-])CC.[Al+3]
Product Categories: Fungicide; Alphabetic; F; FM - FZPesticides; Fungicides; Organophosphorus

Toxicity Data With Reference

1.    

eye-rbt 100 mg SEV

    NTIS**    National Technical Information Service. (Springfield, VA 22161) (Formerly U.S. Clearinghouse for Scientific and Technical Information) OTS0555410 .
2.    

orl-rat LD50:5 g/kg

    FMCHA2    Farm Chemicals Handbook .(Meister Publishing,Willoughy, OH.: )1991,C147.
3.    

skn-rat LD50:>3200 mg/kg

    PEMNDP    Pesticide Manual. 9 (1991),443.
4.    

ipr-rat LD50:550 mg/kg

    PBCPCP    Proceedings-British Crop Protection Conference-Pests and Diseases .(British Crop.,Croydon, UK.: )1977,565.
5.    

orl-mus LD50:3700 mg/kg

    PEMNDP    Pesticide Manual. 9 (1991),443.
6.    

skn-mus LD :>3200 mg/kg

    PBCPCP    Proceedings-British Crop Protection Conference-Pests and Diseases .(British Crop.,Croydon, UK.: )1977,565.
7.    

orl-dog LDLo:>2140 mg/kg

    DOVEAA    Defense des Vegetaux. 33 (1979),224.
8.    

orl-rbt LD50:2680 mg/kg

    PBCPCP    Proceedings-British Crop Protection Conference-Pests and Diseases .(British Crop.,Croydon, UK.: )1977,565.
9.    

skn-rbt LD50:>2 g/kg

    FMCHA2    Farm Chemicals Handbook .(Meister Publishing,Willoughy, OH.: )1991,C147.
10.    

Safety Profile

Moderately toxic by ingestion, skin contact, and intraperitoneal routes. A severe eye irritant. When heated to decomposition it emits toxic vapors of POx.
Hazard Codes:   Xi
The Risk Statements information:
41:  Risk of serious damage to eyes 
The Safety Statements information:
26:  In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 
39:  Wear eye/face protection 
RTECS: SZ9640000

Standards and Recommendations

ACGIH TLV: TWA 2 mg(Al)/m3

Specification

 Fosetyl-aluminum , with CAS number of 39148-24-8, can be called Aluminium tris(ethyl phosphonate) ; Aluminum tris(O-ethyl phosphonate) ; Aluminum tris(ethyl phosphite) ; Fosetyl aluminum ; Fosetyl-aluminium ; Rhone-Poulenc ; Phosphonic acid monoethyl ester aluminum salt .

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