Tetrahedron Letters p. 6069 - 6072 (1987)
Update date:2022-07-29
Topics:
Sasaki, N.Andre
Hashimoto, Chiyomi
Potier, Pierre
Efficient syntheses of (2R)-2-Boc-amino-3-phenylsulfonyl-1-propanol 3 and its enantiomer 9 from L-serine are described.The potential of these compounds in a novel general method for the synthesis of optically pure non protein α-amino acids in both the L and D configurations is exemplified by the preparation of N-Boc-L-and D-homophenylalanine,-norvaline and -norleucine.
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