Page 9 of 16
1
2
3
ACS Catalysis
Polyoxometalate Nanomaterials Using Dioxygen as the
Complex Incorporated into a MOF as a Highly Active Single-
Site Heterogeneous Catalyst for C-Cl Bond Activation. Green
Chem. 2014, 16, 3978–3985.
Terminal Oxidant. Adv. Synth. Catal. 2011, 353, 2988–2998.
Duan, H.; Li, M.; Zhang, G.; Gallagher, J. R.; Huang, Z.; Sun, Y.;
Luo, Z.; Chen, H.; Miller, J. T.; Zou, R.; Lei, A.; Zhao, Y. Single-
Site Palladium(II) Catalyst for Oxidative Heck Reaction:
Catalytic Performance and Kinetic Investigations. ACS Catal.
2015, 5, 3752–3759.
(40)
(58)
(59)
Leubner, S.; Zhao, H.; Van Velthoven, N.; Henrion, M.; Reinsch,
H.; De Vos, D. E.; Kolb, U.; Stock, N. Expanding the Variety of
Zirconium-based Inorganic Building Units for Metal–Organic
Frameworks. Angew. Chem., Int. Ed. 2019, 58, 10995–11000.
Anastasiou, I.; Van Velthoven, N.; Tomarelli, E.; Lombi, A.;
Lanari, D.; Liu, P.; Bals, S.; De Vos, D. E.; Vaccaro, L. C2–H
Arylation of Indoles Catalyzed by Palladium-Containing
Metal-Organic-Framework in γ-Valerolactone. ChemSusChem
2020, 13, 1–7.
Yang, D.; Odoh, S. O.; Borycz, J.; Wang, T. C.; Farha, O. K.; Hupp,
J. T.; Cramer, C. J.; Gagliardi, L.; Gates, B. C. Tuning Zr6 Metal-
Organic Framework (MOF) Nodes as Catalyst Supports: Site
Densities and Electron-Donor Properties Influence Molecular
Iridium Complexes as Ethylene Conversion Catalysts. ACS
Catal. 2016, 6, 235–247.
4
5
6
7
8
(41)
(42)
(43)
(44)
(45)
Huang, Q.; Ke, S.; Qiu, L.; Zhang, X.; Lin, S.
Palladium(II)/Polyoxometalate-Catalyzed
Direct
Alkenylation of Benzofurans under Atmospheric Dioxygen.
ChemCatChem 2014, 6, 1531–1534.
Pascanu, V.; Carson, F.; Solano, M. V.; Su, J.; Zou, X.; Johansson,
M. J.; Martín-Matute, B. Selective Heterogeneous C-H
Activation/Halogenation Reactions Catalyzed by Pd@MOF
Nanocomposites. Chem. - Eur. J. 2016, 22, 3729–3737.
Ferlin, F.; Santoro, S.; Ackermann, L.; Vaccaro, L.
Heterogeneous C-H Alkenylations in Continuous-Flow:
Oxidative Palladium-Catalysis in a Biomass-Derived Reaction
Medium. Green Chem. 2017, 19, 2510–2514.
9
(60)
(61)
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
51
52
53
54
55
56
57
58
59
60
Li, Z.; Schweitzer, N. M.; League, A. B.; Bernales, V.; Peters, A.
W.; Getsoian, A. B.; Wang, T. C.; Miller, J. T.; Vjunov, A.; Fulton,
J. L.; Lercher, J. A.; Cramer, C. J.; Gagliardi, L.; Hupp, J. T.; Farha,
O. K. Sintering-Resistant Single-Site Nickel Catalyst
Supported by Metal-Organic Framework. J. Am. Chem. Soc.
2016, 138, 1977–1982.
Hu, Q.; Liu, X.; Wang, G.; Wang, F.; Li, Q.; Zhang, W. Ag1Pd1
Nanoparticles–Reduced Graphene Oxide as a Highly Efficient
and Recyclable Catalyst for Direct Aryl C−H Olefination. Chem.
- Eur. J. 2017, 23, 17659–17662.
Cirujano, F. G.; Leo, P.; Vercammen, J.; Smolders, S.; Orcajo, G.;
De Vos, D. E. MOFs Extend the Lifetime of Pd(II) Catalyst for
Room Temperature Alkenylation of Enamine-Like Arenes.
Adv. Synth. Catal. 2018, 360, 3872–3876.
(62)
(63)
Manna, K.; Ji, P.; Lin, Z.; Greene, F. X.; Urban, A.; Thacker, N. C.;
Lin, W. Chemoselective Single-Site Earth-Abundant Metal
Catalysts at Metal-Organic Framework Nodes. Nat. Commun.
2016, 7, 1–11.
Bernales, V.; Yang, D.; Yu, J.; Gümüşlu, G.; Cramer, C. J.; Gates,
B. C.; Gagliardi, L. Molecular Rhodium Complexes Supported
on the Metal-Oxide-like Nodes of Metal Organic Frameworks
and on Zeolite HY: Catalysts for Ethylene Hydrogenation and
Dimerization. ACS Appl. Mater. Interfaces 2017, 9, 33511–
33520.
Otake, K. I.; Cui, Y.; Buru, C. T.; Li, Z.; Hupp, J. T.; Farha, O. K.
Single-Atom-Based Vanadium Oxide Catalysts Supported on
Metal-Organic Frameworks: Selective Alcohol Oxidation and
Structure-Activity Relationship. J. Am. Chem. Soc. 2018, 140,
8652–8656.
Van Velthoven, N.; Waitschat, S.; Chavan, S. M.; Liu, P.;
Smolders, S.; Vercammen, J.; Bueken, B.; Bals, S.; Lillerud, K.
P.; Stock, N.; De Vos, D. E. Single-Site Metal–Organic
Framework Catalysts for the Oxidative Coupling of Arenes via
C–H/C–H Activation. Chem. Sci. 2019, 10, 3616–3622.
Deria, P.; Bury, W.; Hod, I.; Kung, C. W.; Karagiaridi, O.; Hupp,
J. T.; Farha, O. K. MOF Functionalization via Solvent-Assisted
Ligand Incorporation: Phosphonates vs Carboxylates. Inorg.
Chem. 2015, 54, 2185–2192.
Fu, G.; Bueken, B.; De Vos, D. Zr-Metal-Organic Framework
Catalysts for Oxidative Desulfurization and Their
Improvement by Postsynthetic Ligand Exchange. Small
Methods 2018, 2, 1800203.
Zhang, W.; Bu, A.; Ji, Q.; Min, L.; Zhao, S.; Wang, Y.; Chen, J. PKa-
Directed Incorporation of Phosphonates into MOF-808 via
Ligand Exchange: Stability and Adsorption Properties for
Uranium. ACS Appl. Mater. Interfaces 2019, 11, 33931–33940.
Furukawa, H.; Gándara, F.; Zhang, Y.-B.; Jiang, J.; Queen, W. L.;
Hudson, M. R.; Yaghi, O. M. Water Adsorption in Porous Metal-
Organic Frameworks and Related Materials. J. Am. Chem. Soc.
2014, 136, 4369–4381.
Thür, R.; Van Velthoven, N.; Lemmens, V.; Bastin, M.;
Smolders, S.; De Vos, D.; Vankelecom, I. F. J. Modulator-
Mediated Functionalization of MOF-808 as a Platform Tool to
Create High-Performance Mixed-Matrix Membranes. ACS
Appl. Mater. Interfaces 2019, 11, 44792–44801.
Howarth, A. J.; Liu, Y.; Li, P.; Li, Z.; Wang, T. C.; Hupp, J. T.;
Farha, O. K. Chemical, Thermal and Mechanical Stabilities of
Metal-Organic Frameworks. Nat. Rev. Mater. 2016, 1, 1–15.
Healey, K.; Liang, W.; Southon, P. D.; Church, T. L.;
D’Alessandro, D. M. Photoresponsive Spiropyran-
Functionalised MOF-808: Postsynthetic Incorporation and
Light Dependent Gas Adsorption Properties. J. Mater. Chem. A
2016, 4, 10816–10819.
(46)
(47)
Liu, M.; Wu, J.; Hou, H. Metal–Organic Framework (MOF)-
Based Materials as Heterogeneous Catalysts for C−H Bond
Activation. Chem. - Eur. J. 2019, 25, 2935–2948.
Otake, K.; Ye, J.; Mandal, M.; Islamoglu, T.; Buru, C. T.; Hupp, J.
T.; Delferro, M.; Truhlar, D. G.; Cramer, C. J.; Farha, O. K.
Enhanced Activity of Heterogeneous Pd(II) Catalysts on Acid-
Functionalized Metal–Organic Frameworks. ACS Catal. 2019,
9, 5383–5390.
Copéret, C.; Comas-Vives, A.; Conley, M. P.; Estes, D. P.;
Fedorov, A.; Mougel, V.; Nagae, H.; Núnez-Zarur, F.; Zhizhko,
P. A. Surface Organometallic and Coordination Chemistry
toward Single-Site Heterogeneous Catalysts: Strategies,
Methods, Structures, and Activities. Chem. Rev. 2016, 116,
323–421.
(64)
(65)
(48)
(49)
Cui, X.; Li, W.; Ryabchuk, P.; Junge, K.; Beller, M. Bridging
Homogeneous
and
Heterogeneous
Catalysis
by
Heterogeneous Single-Metal-Site Catalysts. Nat. Catal. 2018,
1, 385–397.
Corma, A.; García, H.; Llabrés i Xamena, F. X. Engineering
Metal Organic Frameworks for Heterogeneous Catalysis.
Chem. Rev. 2010, 110, 4606–4655.
Gascon, J.; Corma, A.; Kapteijn, F.; Llabrés I Xamena, F. X. Metal
Organic Framework Catalysis: Quo Vadis? ACS Catal. 2014, 4,
361–378.
Rogge, S. M. J.; Bavykina, A.; Hajek, J.; Garcia, H.; Olivos-Suarez,
A. I.; Sepúlveda-Escribano, A.; Vimont, A.; Clet, G.; Bazin, P.;
Kapteijn, F.; Daturi, M.; Ramos-Fernandez, E. V.; Llabrés
Xamena, F. X. I.; Van Speybroeck, V.; Gascon, J. Metal-Organic
and Covalent Organic Frameworks as Single-Site Catalysts.
Chem. Soc. Rev. 2017, 46, 3134–3184.
(66)
(67)
(68)
(69)
(70)
(50)
(51)
(52)
(53)
(54)
Cirujano, F. G. Engineered MOFs and Enzymes for the
Synthesis
of
Active
Pharmaceutical
Ingredients.
ChemCatChem 2019, 11, 5671–5685.
Dhakshinamoorthy, A.; Asiri, A. M.; Garcia, H. Formation of C-
C and C-Heteroatom Bonds by C-H Activation by Metal
Organic Frameworks as Catalysts or Supports. ACS Catal.
2019, 9, 1081–1102.
Oien, S.; Agostini, G.; Svelle, S.; Borfecchia, E.; Lomachenko, K.
A.; Mino, L.; Gallo, E.; Bordiga, S.; Olsbye, U.; Lillerud, K. P.;
Lamberti, C. Probing Reactive Platinum Sites in UiO-67
Zirconium Metal–Organic Frameworks. Chem. Mater. 2015,
27, 1042–1056.
Li, X.; Van Zeeland, R.; Maligal-Ganesh, R. V.; Pei, Y.; Power, G.;
Stanley, L.; Huang, W. Impact of Linker Engineering on the
Catalytic Activity of Metal-Organic Frameworks Containing
Pd(II)-Bipyridine Complexes. ACS Catal. 2016, 6, 6324–6328.
Chen, L.; Rangan, S.; Li, J.; Jiang, H.; Li, Y. A Molecular Pd(II)
(55)
(71)
(72)
(56)
(57)
(73)
Reinsch, H.; Waitschat, S.; Chavan, S. M.; Lillerud, K. P.; Stock,
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