Journal of Organic Chemistry p. 4360 - 4369 (1993)
Update date:2022-08-03
Topics:
Sura, Tushar P.
MacDowell, Denis W. H.
The inability to observe Cope rearrangement products at elevated temperatures for diethyl α-allyl-2-naphthalenemalonate (1) and diethyl α-allyl-9-phenanthrenemalonate (2) does not extend to the analogous systems resulting from replacement of the aromatic units by 2- and 3-benzothiophene nuclei.Thermal rearrangement of diethyl α-allyl-3-benzothiophenemalonate (5) at 215-255 deg C for 11 h produces the expected Cope rearrangement product diethyl 2-allyl-3-benzothiophenemalonate (10) (8percent) accompanied by trans- and cis-ethyl 2,3-dihydro-1-(ethoxycarbonyl)-1H-benzocyclopenta
JiangXi Hong Run Chemical Co., Ltd
Contact:+86-0791-88521351
Address:XingHuo industrial zone in YongXiu county
Chengdu Green Young Biopharmaceutical INC
Contact:+86-28-85337952
Address:1-B-26,Tianhe Industry Park, No.1480 of Tianfu Road,Chengdu,P.R.China,610000
Nantong Auxin Electronic Technology Co., LTD
Contact:86-513-88760026
Address:NO.5-1, Aoxin Road, Haian Hi-tech Development Zone, Jiangsu Province, China
Contact:+86-731-84427351
Address:154 JIANXIANG SOUTH ROAD
Hubei Xiangxi Chemical Industry Co.,Ltd
Contact:+86-710-3454830
Address:No.7, Daqing East Road, Xiangfan City, Hubei Province, China
Doi:10.1134/S0023158413060050
(2013)Doi:10.1016/S0040-4039(00)93386-0
(1993)Doi:10.1016/j.jinorgbio.2011.09.034
(2012)Doi:10.1021/jm00068a022
(1993)Doi:10.1021/om0605276
(2006)Doi:10.1016/S0020-1693(00)87938-4
(1991)